Highly Transparent Fire-resistant Coatings with Intumescent Three-source Integration

Zeng, Xiao-Liang; Lan, Xin-Sheng; Wang, Yan; Zhang, Lin; Guo, De-Ming; Zhao, Hai-Bo

doi:10.1007/s10118-024-3100-1

Chin J Polym Sci

2024

DOI: 10.1007/s10118-024-3100-1

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Highly Transparent Fire-resistant Coatings with Intumescent Three-source Integration

Xiao-Liang Zeng,

Xin-Sheng Lan,

Yan Wang

et al.

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Cited by 4 publications

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Eco‐Friendly Self‐Adaptive Catalytic Strategy for Plastics Lifecycles: Achieving Green Preparation, Superior Flame Retardancy, and Self‐Driven Sustainability

Wu,

Zhao,

Chen

et al. 2024

Adv Funct Materials

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Semi‐rigid polyurethane foams (SPUF) with high deformation resistance and strength are indispensable for cushioning applications. However, for high fire risk and cascaded pollutant effects, overused multifarious additives and foam wastes exacerbate global environmental concerns. One option to address this issue is to develop eco‐friendly multifunctional flame retardants that participate in the material lifecycles of preparation, safe service, waste management, and sustainable recycling. Herein, a novel self‐adaptive catalytic strategy is reported that exploits the temperature and agent structure‐responsive catalytic ability of eco‐friendly sodium propionate (SP), reconciling the often‐conflicting properties of fabrication and recycling while effectively mitigating combustion risks and additive pollution. The adaptive catalytic function of SP impressively involves all aspects of foam life cycles: 1) catalyzing foaming without complex/hazardous catalysts; 2) providing superior flame‐retardant efficiency with a high limiting oxygen index of 25.5% without relying on traditional flame retardants; 3) promoting in situ network fragmentation and reorganization into strong adhesives (5.8 MPa); and 4) further recycling of the newly formed adhesives in a self‐driven sustainable manner. A novel green strategy is presented that addresses fire hazards, plastic pollution, and the unsustainability of recycling, minimizing the ecological risks of foam, which will positively impact future sustainable material design involving diverse additives.

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Eco‐Friendly Self‐Adaptive Catalytic Strategy for Plastics Lifecycles: Achieving Green Preparation, Superior Flame Retardancy, and Self‐Driven Sustainability

Wu,

Zhao,

Chen

et al. 2024

Adv Funct Materials

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Phytic acid-induced durable fire-proof and hydrophobic complex coating for versatile cotton fabrics

Yang,

Yan,

Huang

et al. 2024

International Journal of Biological Macromolecules

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Selectively self-recyclable, highly transparent and fire-safe polycarbonate plastic enabled by thermally responsive phosphonium-phosphate

Deng,

Chen,

et al. 2024

Mater. Horiz.

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Highly Transparent Fire-resistant Coatings with Intumescent Three-source Integration

Cited by 4 publications

References 48 publications

Eco‐Friendly Self‐Adaptive Catalytic Strategy for Plastics Lifecycles: Achieving Green Preparation, Superior Flame Retardancy, and Self‐Driven Sustainability

Eco‐Friendly Self‐Adaptive Catalytic Strategy for Plastics Lifecycles: Achieving Green Preparation, Superior Flame Retardancy, and Self‐Driven Sustainability

Phytic acid-induced durable fire-proof and hydrophobic complex coating for versatile cotton fabrics

Selectively self-recyclable, highly transparent and fire-safe polycarbonate plastic enabled by thermally responsive phosphonium-phosphate

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