Highly Transparent Red Organic Light-Emitting Diodes with AZO/Ag/AZO Multilayer Electrode

Abstract

Free-form factor optoelectronics is becoming more important for various applications. Specifically, flexible and transparent optoelectronics offers the potential to be adopted in wearable devices in displays, solar cells, or biomedical applications. However, current transparent electrodes are limited in conductivity and flexibility. This study aims to address these challenges and explore potential solutions. For the next-generation transparent conductive electrode, Al-doped zinc oxide (AZO) and silver (AZO/Ag/AZO) deposited by in-line magnetron sputtering without thermal treatment was investigated, and this transparent electrode was used as a transparent organic light-emitting diode (OLED) anode to maximize the transparency characteristics. The experiment and simulation involved adjusting the thickness of Ag and AZO and OLED structure to enhance the transmittance and device performance. The AZO/Ag/AZO with Ag of 12 nm and AZO of 32 nm thickness achieved the results of the highest figure of merit (FOM) (Φ550 = 4.65 mΩ−1) and lowest roughness. The full structure of transparent OLED (TrOLED) with AZO/Ag/AZO anode and Mg:Ag cathode reached 64.84% transmittance at 550 nm, and 300 cd/m2 at about 4 V. The results demonstrate the feasibility of adopting flexible substrates, such as PET, without the need for thermal treatment. This research provides valuable insights into the development of transparent and flexible electronic devices.

Overcoming Challenges in OLED Technology for Lighting Solutions

“…The metals frequently used in multilayer structures are Ag and Au, while the most common oxide layers are (WO 3 ) and ZnO, but also ITO or FTO are used. Various configurations have been reported in the literature; the most commonly used are MoO 3 /Ag or Au /MoO 3 [164][165][166][167], MoO 3 /Ag/WO 3 [143], ZnS/Ag/WO 3 [168], ZnS/Ag/MoO 3 [169], ZnS/Ag/ZnS [170], ZnO/Ag or Au/ZnO [171][172][173][174][175], FTO/Ag/FTO [176], ITO/chAg or Au/ITO [175,177], and AZO/chAg/AZO [178].…”