2005
DOI: 10.1002/pssc.200461100
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Historical perspective on the discovery of porous silicon

Abstract: PACS 01.65.+g, 82.45.Vp This paper recollects the research undertaken in the field of electrochemistry of semiconductors, leading to the discovery of porous silicon, some 50 years ago. Some of the attendees at the PSST-2004 were interested in the "time line" of related events. Original notebooks with actual dates were left in the care of Bell Telephone Laboratories. Carbon copies were not made and regularly filed (as done at some other research laboratories). Germanium point-contact transistorsThey were fa… Show more

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Cited by 19 publications
(7 citation statements)
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“…Ingeborg Uhlir first discovered and reported the formation of porous silicon films by electrochemical etching in 1956 [92] . Silicon‐based nanopores can be obtained by directly irradiating focused ions or electron beams on silicon dioxide (SiO 2 ) or silicon nitride (SiN x ) films [93] .…”
Section: Nanoporementioning
confidence: 99%
See 1 more Smart Citation
“…Ingeborg Uhlir first discovered and reported the formation of porous silicon films by electrochemical etching in 1956 [92] . Silicon‐based nanopores can be obtained by directly irradiating focused ions or electron beams on silicon dioxide (SiO 2 ) or silicon nitride (SiN x ) films [93] .…”
Section: Nanoporementioning
confidence: 99%
“…Ingeborg Uhlir first discovered and reported the formation of porous silicon films by electrochemical etching in 1956. [92] Silicon-based nanopores can be obtained by directly irradiating focused ions or electron beams on silicon dioxide (SiO 2 ) or silicon nitride (SiN x ) films. [93] One specific method of fabrication is first to remove the SiO 2 , or SiN x , covering the top and bottom surfaces of the silicon wafer and then deeply etch the exposed silicon surface with KOH.…”
Section: Silicon-based Nanoporesmentioning
confidence: 99%
“…Porous silicon (PSi) was first discovered in 1956 by researchers at Bell Laboratories interested in electropolishing of c-Si surface [132]. In the late 1980s, PSi was rediscovered as a nanostructured material by Canham [133] and Lehmann and G€ osele [134]; they suggested that PSi exhibits quantum confinement effect due to reduced dimensions of Si crystallites.…”
Section: Electrochemically Etched Si (Porous Si)mentioning
confidence: 99%
“…They used an electrolyte containing hydrofluoric acid, which left a spongelike nanocrystalline silicon structure on the wafer. 1 This roughened, chemically reactive surface makes the material a versatile substrate for biosensors.…”
mentioning
confidence: 99%