In this study, the occurrence and distribution of 16 polycyclic aromatic hydrocarbons (PAHs), listed by the United States Environmental Protection Agency (US EPA), were investigated in surface sediment samples from the Hun River, northeast China. The data was then used to assess the potential ecological risk. [g,h,i]perylene) showed that they had been emitted from a number of different sources, especially the pyrolytic emissions. The results of the ecological risk assessment, which compared the PAH concentrations with the effect range low (ERL) and the effect range median (ERM) values, indicated that several individual PAH concentrations at four sites in the downstream section of the Hun River were higher than the ERM, suggesting that there was a potential ecological risk in these areas.