2015
DOI: 10.1002/adma.201500493
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Holey Tungsten Oxynitride Nanowires: Novel Anodes Efficiently Integrate Microbial Chemical Energy Conversion and Electrochemical Energy Storage

Abstract: Holey tungsten oxynitride nanowires with superior conductivity, good biocompatibility, and good stability achieve excellent performance as anodes for both asymmetric supercapacitors and microbial fuel cells. Moreover, an innovative system is devised based on these as-prepared tungsten oxynitride anodes, which can simultaneously realize both energy conversion from chemical to electric energy and its storage.

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Cited by 188 publications
(106 citation statements)
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“…Unfortunately, the low ionic conductivity, high environmental toxicity and expensive nature of these organic electrolytes seriously hinder their practical applications in high-performance flexible SCs. Alternatively, constructing asymmetric supercapacitors (ASCs) with aqueous gel polymer electrolytes are recently emerging as an available strategy to gain the energy density of flexible SCs by increasing the cell potential from 1 to 2 V [15,[17][18][19][20][21][22][23]. Moreover, in comparison to organic electrolytes, aqueous gel polymer electrolytes have higher ionic conductivity and much less toxicity, which could offer high power density and great promise for wearable devices [6].…”
Section: Introductionmentioning
confidence: 99%
“…Unfortunately, the low ionic conductivity, high environmental toxicity and expensive nature of these organic electrolytes seriously hinder their practical applications in high-performance flexible SCs. Alternatively, constructing asymmetric supercapacitors (ASCs) with aqueous gel polymer electrolytes are recently emerging as an available strategy to gain the energy density of flexible SCs by increasing the cell potential from 1 to 2 V [15,[17][18][19][20][21][22][23]. Moreover, in comparison to organic electrolytes, aqueous gel polymer electrolytes have higher ionic conductivity and much less toxicity, which could offer high power density and great promise for wearable devices [6].…”
Section: Introductionmentioning
confidence: 99%
“…Carbon nanomaterials are known for their high specific surface area (SSA), which allows ions to be electrostatically adsorbed on its surface. [57][58][59] In case of metal nitrides there will be complete replacement of oxygen (O 2À ) atoms in octahedral position of lattice with nitrogen (N 3À ) atoms, whereas in. [36][37][38][39][40][41] pseudocapacitive mechanism is mainly exhibited by MOs, [42][43][44] MNs, [45][46][47] MSs, [48][49][50][51] CPs, [52,53] and MONs.…”
Section: Introductionmentioning
confidence: 99%
“…[54,55] The energy density and specific capacitance associated with this behaviour is higher than carbon materials. [57,58] Though MNs are reliable as SC electrode materials, they are poor in terms of cycle life and rate performances. [56] Currently, new class of emerging novel material including MONs, MNs and their composites are being synthesized and investigated for their SC behaviour.…”
Section: Introductionmentioning
confidence: 99%
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“…[1][2][3][4][5][6][7][8] The rational design and fabrication of integrated systems with the aim of achieving maximum functionality at minimized size and weight are being intensively pursued. [21][22][23][24][25][26] Recently, some integrated systems of energy storage devices with add-on functional modules, such as solar cells, [ 27,28 ] piezoelectric, [29][30][31] and triboelectric nanogenerator, [32][33][34] photodetector [ 35 ] as well as memristor, [ 36 ] have been successfully fabricated. [21][22][23][24][25][26] Recently, some integrated systems of energy storage devices with add-on functional modules, such as solar cells, [ 27,28 ] piezoelectric, [29][30][31] and triboelectric nanogenerator, [32][33][34] photodetector [ 35 ] as well as memristor, [ 36 ] have been successfully fabricated.…”
Section: Introductionmentioning
confidence: 99%