2023
DOI: 10.1002/adfm.202309135
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Homogeneous and Heterogeneous Self‐Assembly of Luminescent Pyromellitic Dianhydride‐Based Charge‐Transfer Complexes

Lulu Zhang,
Zuofang Feng,
Hongli Zhang
et al.

Abstract: Using easily hydrolyzable brominated pyromellitic dianhydride (PMDA) as an electron acceptor, a wide variety of structurally stable binary organic charge‐transfer (CT) microcrystals that are stabilized by dominant intermolecular CT interactions is achieved. By varying the electron‐donating abilities of π‐electron compounds, the resulting single crystalline CT assemblies display tailorable fluorescence emissions spanning from green to near‐infrared. Upon implantation of a π‐electron donor anthracene (An) into f… Show more

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