Homolytic reaction of 1-hydrosilatrane with perfluoroalkyl iodides

Воронков, М. Г.; Petukhov, L. P.; Rakhlin, V. I.; Baryshok, V. P.; Shterenberg, B. Z.; Мирсков, Р. Г.; Pestunovich, V. A.

doi:10.1007/bf00963452

Cited by 5 publications

(2 citation statements)

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“…We report herein the first examples of such compounds, the neutral pentacoordinate silicon(IV) complexes 1 (SiClSONC skeleton) and 2 (SiISONC skeleton). Compound 2 is the first higher coordinate silicon(IV) complex with an SiI bond that has been structurally characterized by single‐crystal X‐ray diffraction,5, 6 and 3 , with its trifluoromethanesulfonato ligand, contains the novel SiSO 2 NC skeleton.…”

Section: Methodsmentioning

confidence: 99%

Pentacoordination of Silicon by Five Different Ligand Atoms: Neutral Silicon(IV) Complexes with SiClSONC and SiISONC Skeletons

et al. 2007

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Alle fünfe: Ein fünffach koordiniertes Siliciumzentrum mit fünf unterschiedlichen Ligandatomen (SiClSONC‐ und SiISONC‐Gerüste) wurde in Form des neutralen SiIV‐Komplexes 1 und des analogen Iodo‐Derivats erhalten. Beide Komplexe sind im Festkörper und in Lösung stabil. Der Chloroligand in 1 kann leicht ausgetauscht werden, sodass eine Reihe von fünffach koordinierten Siliciumkomplexen zugänglich sein sollte.

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Section: Methodsmentioning

confidence: 99%

Pentacoordination of Silicon by Five Different Ligand Atoms: Neutral Silicon(IV) Complexes with SiClSONC and SiISONC Skeletons

et al. 2007

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“…Note that isocyanate 6 is unstable, which is why it could not be isolated in the individual state even at considerable temperature lowering as well as when N,N-dimethyI-N',N'-bis(trimethylsilyl)hydrazine (8) -20 *C [6] -7a + 7b…”

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confidence: 99%

Synthesis and chemical transformations of silicon-containing derivatives ofN,N-dimethylhydrazine

et al. 1999

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Reactions of carbofunctional organosilicon compounds with N, N-dimethyI-N'-trimethylsilylhydrazine and N,N-dimethyl-N',N'-bis(trimethylsilyl)hydra~ne were studied.The composition and structure of the reaction products were found to be dependent on the reagent nature and the reaction conditions. 1,4-Dimethylamino-2,2,5,5-tetramethyl-l,4-diaza-2,5-disilaeyclohexane, a first representative of a new type of 2,5-disilapiperazines, was synthesized. A scheme of its formation was proposed.

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