In order to solve the problem that the dynamic programming of traditional intelligent scheduling algorithm is not perfect, which leads to the operation result taking too long, the author proposes an intelligent scheduling algorithm for enterprise human resources based on big data. This research creates an effective planning model based on big data, realizes the effective business plan of human resources, develops the advanced instruction of the intelligent scheduling algorithm, and proposed intelligent scheduling algorithm based on table precedence. The results showed that the average time of the experimental group was 7.261s shorter than the control group in the 20 stages of the data fusion test. The results show that, compared with the traditional intelligent scheduling algorithm, the intelligent scheduling algorithm proposed by the author can reduce the time required for data fusion and calculation in the stage, and the performance of the intelligent scheduling algorithm based on the previous table is better than those. Practice has proven that the intelligent scheduling algorithm based on the table can help reduce the work of intelligent scheduling of business human resources based on big data.