The U.S. airline network is one of the most advanced transportation infrastructures in the world. It is a complex geospatial structure that sustains a variety of dynamics including commercial, public, and military operations and services. We study the U.S. domestic intercity passenger air transportation network using a weighted complex network methodology, in which vertices represent cities and edges represent intercity airline connections weighted by average daily passenger traffic, non-stop distance, and average oneway fares. We find that U.S. intercity passenger air transportation network is a small-world network accompanied by dissortative mixing patterns and rich-club phenomenon, implying that large degree cities (or hub cities) tend to form high traffic volume interconnections among each other and large degree cities tend to link to a large number of small degree cities. The interhub air connections tend to form interconnected triplets with high traffic volumes, long non-stop distances, and low average one-way fares. The structure of the U.S. airline network reflects the dynamic integration of pre-existing urban and national transportation infrastructure with the competitive business strategies of commercial airlines. In this paper we apply an emerging methodology to representing, analyzing, and modeling the complex interactions associated with the physical and human elements of the important U.S. national air transport and services infrastructure.