Thermoelectric
textiles, constructed from thermoelectric
materials
and fabric, offer unique advantages compared to other types as they
facilitate thermal energy harvesting from the human body and conform
exceptionally well to dynamic body curves. This underscores their
potential for on-body applications in electricity generation. In this
investigation, we present a tellurium–free polymer-based textile
thermoelectric prototype manufactured through a cost-effective method
known as the solution drop-casting process. Two organic polymers,
PEDOT:PSS
and PVDF, are judiciously employed at optimized concentrations. At
300 K, the resulting PEDOT:PSS + PVDF/fabric thermoelectric film could
exhibit an impressive output power factor of 60 nW/mK2.
The processed thermoelectric film could retain its electronic properties
after 500 bending cycles, which confirms its extraordinarily flexible
nature. When subjected to a temperature gradient of 35 K, the textile
thermoelectric prototype could generate a noteworthy output voltage
and power of 3.8 mV and 2.7 nW, respectively, at 300 K. Importantly,
when in contact with a human wrist and subjected to a temperature
difference of ∼3 K, the prototype produced a 0.2 mV output
voltage, which is reliable. Above all, the prototype exhibited an
outstanding output voltage of approximately 13 mV, when its cold-end
and hot-end were at 236 and 277 K, respectively. This corroborated
the compatibility and superior energy generation performance of the
investigated textile thermoelectrics under cold environmental conditions.
Our study emphasizes the feasibility of Te-free, nontoxic polymer-based
textile thermoelectric fabric for power generation using the human
body and other low-grade heat available below and at room temperature.