Hybrid 3D printing for highly efficient nanoparticle micropatterning

Jambhulkar, Sayli; Ravichandran, Dharneedar; Sundaravadivelan, Barath; Song, Kenan

doi:10.1039/d3tc00168g

Cited by 4 publications

(3 citation statements)

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“…S1). This study presents a notable advancement in line with our prior publications, 22,23 which focused on utilizing templates and patterned substrates to fabricate functional electronic devices using MXene NPs. Herein, we demonstrate the facile fabrication of template-free MXene-based electronics without using additive or rheology modifiers.…”

supporting

confidence: 62%

3D printing aqueous Ti₃C₂T_x inks for MXene-based energy devices

Fagade,

Patil,

Thummalapalli

et al. 2023

Mater. Adv.

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supporting

confidence: 62%

3D printing aqueous Ti₃C₂T_x inks for MXene-based energy devices

Fagade,

Patil,

Thummalapalli

et al. 2023

Mater. Adv.

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“…In comparison, the nanoscale carbons (e.g., Gr) of metal carbide/carbonitride (e.g., MXenes) are more flexible with proper pre‐processing, such as colloid dispersion or mixing with fluidic monomers. [ 132 ] Polymers, on the other hand, are compatible with the majority of 3D printing mechanisms. As the feedstock of electrolytes, polymers can exist in dissolved solutions, dispersed particles in curable monomers, melts to disperse powders, and as binders in laser‐printing techniques.…”

Section: Current Challenges and Future Perspectivesmentioning

confidence: 99%

3D Printing‐Enabled Design and Manufacturing Strategies for Batteries: A Review

Fonseca,

Thummalapalli,

Jambhulkar

et al. 2023

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Lithium‐ion batteries (LIBs) have significantly impacted the daily lives, finding broad applications in various industries such as consumer electronics, electric vehicles, medical devices, aerospace, and power tools. However, they still face issues (i.e., safety due to dendrite propagation, manufacturing cost, random porosities, and basic & planar geometries) that hinder their widespread applications as the demand for LIBs rapidly increases in all sectors due to their high energy and power density values compared to other batteries. Additive manufacturing (AM) is a promising technique for creating precise and programmable structures in energy storage devices. This review first summarizes light, filament, powder, and jetting‐based 3D printing methods with the status on current trends and limitations for each AM technology. The paper also delves into 3D printing‐enabled electrodes (both anodes and cathodes) and solid‐state electrolytes for LIBs, emphasizing the current state‐of‐the‐art materials, manufacturing methods, and properties/performance. Additionally, the current challenges in the AM for electrochemical energy storage (EES) applications, including limited materials, low processing precision, codesign/comanufacturing concepts for complete battery printing, machine learning (ML)/artificial intelligence (AI) for processing optimization and data analysis, environmental risks, and the potential of 4D printing in advanced battery applications, are also presented.

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“…Many other rapid prototyping techniques, such as stamping, wrinkling, μCLIP, inkjet printing, FDM, and SLA 3D printing, have shown the ability to integrate multi-material systems and pattern different nanoparticles into 2D surface patterns or 3D complex structures. [62,65,204,439,461,209] Challenges still exist, including assembling isotropic and anisotropic building blocks, understanding underlying assembly mechanisms, and developing superstructure phase diagrams.…”

Section: Multi-materials To Enable Patterning Versatilitymentioning

confidence: 99%

Nanoparticle Assembly: From Self‐Organization to Controlled Micropatterning for Enhanced Functionalities

Jambhulkar,

Ravichandran,

Zhu

et al. 2023

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Nanoparticles form long‐range micropatterns via self‐assembly or directed self‐assembly with superior mechanical, electrical, optical, magnetic, chemical, and other functional properties for broad applications, such as structural supports, thermal exchangers, optoelectronics, microelectronics, and robotics. The precisely defined particle assembly at the nanoscale with simultaneously scalable patterning at the microscale is indispensable for enabling functionality and improving the performance of devices. This article provides a comprehensive review of nanoparticle assembly formed primarily via the balance of forces at the nanoscale (e.g., van der Waals, colloidal, capillary, convection, and chemical forces) and nanoparticle‐template interactions (e.g., physical confinement, chemical functionalization, additive layer‐upon‐layer). The review commences with a general overview of nanoparticle self‐assembly, with the state‐of‐the‐art literature review and motivation. It subsequently reviews the recent progress in nanoparticle assembly without the presence of surface templates. Manufacturing techniques for surface template fabrication and their influence on nanoparticle assembly efficiency and effectiveness are then explored. The primary focus is the spatial organization and orientational preference of nanoparticles on non‐templated and pre‐templated surfaces in a controlled manner. Moreover, the article discusses broad applications of micropatterned surfaces, encompassing various fields. Finally, the review concludes with a summary of manufacturing methods, their limitations, and future trends in nanoparticle assembly.

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Hybrid 3D printing for highly efficient nanoparticle micropatterning

Abstract: Fused deposition modeling (FDM) 3D printing often generates inevitable surface phenomena/defects called the "staircase effect," which involves anisotropic material texture, rough surface topology, and interlayer voids. Besides, the staircase morphology...

Cited by 4 publications

References 50 publications

3D printing aqueous Ti₃C₂T_x inks for MXene-based energy devices

3D printing aqueous Ti₃C₂T_x inks for MXene-based energy devices

3D Printing‐Enabled Design and Manufacturing Strategies for Batteries: A Review

Nanoparticle Assembly: From Self‐Organization to Controlled Micropatterning for Enhanced Functionalities

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Hybrid 3D printing for highly efficient nanoparticle micropatterning

Abstract: Fused deposition modeling (FDM) 3D printing often generates inevitable surface phenomena/defects called the "staircase effect," which involves anisotropic material texture, rough surface topology, and interlayer voids. Besides, the staircase morphology...

Cited by 4 publications

References 50 publications

3D printing aqueous Ti3C2Tx inks for MXene-based energy devices

3D printing aqueous Ti3C2Tx inks for MXene-based energy devices

3D Printing‐Enabled Design and Manufacturing Strategies for Batteries: A Review

Nanoparticle Assembly: From Self‐Organization to Controlled Micropatterning for Enhanced Functionalities

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Product

Resources

About

3D printing aqueous Ti₃C₂T_x inks for MXene-based energy devices

3D printing aqueous Ti₃C₂T_x inks for MXene-based energy devices