Hybrid Cu-Fe/ZSM-5 Catalyst Prepared by Liquid Ion-Exchange for NOx Removal by NH3-SCR Process

Abstract

A series of Cu/ZSM-5, Fe/ZSM-5, and Cu-Fe/ZSM-5 catalysts (Si/Al in ZSM-5 = 25) were prepared by different metal loadings using the liquid ion-exchange method. Several characterization methods were conducted to explore the effects of metals on the physical and chemical properties of catalysts. Meanwhile, the electron paramagnetic resonance method is also used to assess the copper and/or iron elements’ coordination and valence state at intersections or in channels of ZSM-5. The metal-loading effects of all catalysts on the catalytic activities were studied for the removal of NOx in a fixed-bed flow reactor using selective catalytic reduction with ammonia (NH3-SCR). The results showed that the iron’s addition could markedly broaden the operation temperature range of the Cu/ZSM-5 catalyst for NH3-SCR between 200 and 550°C due to the presence of more isolated Cu2+ ions as well as additional oligomeric Fe3+ active sites and FexOy oligomeric species. This paper gives a facile and straightforward way to synthesize the practical-promising catalyst applied in NH3-SCR technology to control NOx emissions.

Biosensor nanoarchitectonics of Cu–Fe-nanoparticles/Zeolite-A/Graphene nanocomposite for enhanced electrooxidation and dopamine detection

“…To the mixture add 5 ml of 30 mM NaBH 4 and stirred at 65ᵒ C for 5–6 h which produces a black precipitate of Cu–Fe NP/ZEA/Gr. It is cooled, filtered and, dried at room temperature for 24 h to produce the dry powder [ 4 , 12 ].…”