2006
DOI: 10.1007/s11244-006-0025-6
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Hybrid materials for immobilization of MP-11 catalyst

Abstract: Microperoxidase-11(MP-11) has been immobilized for the first time in hybrid periodic mesoporous organosilica (PMO) materials and in a nano-crystalline metal organic framework (MOF). Microperoxidase-11 was physically absorbed from solution into the periodic mesoporous organosilica MBS and functionalized derivatives of MBS as well as in the 3-dimensional [Cu(OOC-C 6 H 4 -C 6 H 4 -COO)AE½ C 6 H 12 N 2 ] n metal organic framework. The conversion of Amplex Ò UltraRed and methylene blue to their respective oxidation… Show more

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Cited by 116 publications
(61 citation statements)
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“…The authors also prepared horseradish peroxidase/ZIF‐8, lipase/ZIF‐8, and Cyt c/ZIF‐10 nanocomposites using the same method. This entrapment method is distinct from other works that immobilized small proteins/enzymes with MOFs …”
Section: Nmofs For Therapeutic Applicationsmentioning
confidence: 96%
“…The authors also prepared horseradish peroxidase/ZIF‐8, lipase/ZIF‐8, and Cyt c/ZIF‐10 nanocomposites using the same method. This entrapment method is distinct from other works that immobilized small proteins/enzymes with MOFs …”
Section: Nmofs For Therapeutic Applicationsmentioning
confidence: 96%
“…A widely used technique for enzyme protection is by inserting the enzymes in the presynthesized MOF particles through pore insertion (67). The postinfiltration method is sufficiently reported to accommodate various biomacromolecules with different sizes in a range of MOFs (20,68,69). One substantial drawback of this approach is that biomolecules significantly larger than the pore size of the host could not be encapsulated.…”
Section: Exogenous Bioaugmentationmentioning
confidence: 99%
“…MP 11 was immobilized in hybrid periodic mesoporous organosilica materials and in a nano-crystalline metal organic [Cu(OOC-C6H4-C6H4-COO)AE C6H12N2] n framework. The conversion of Amplex-Ultra Red and Methylene Blue to their respective oxidation products catalyzed successfully in the presence of immobilized MP 11 (Pisklak et al 2006).…”
Section: Microperoxidase 11mentioning
confidence: 99%