The multiobjective knapsack problem (MOKP) is an important combinatorial problem that arises in various applications, including resource allocation, computer science and finance. When tackling this problem by evolutionary multiobjective optimization algorithms (EMOAs), it has been demonstrated that traditional recombination operators acting on binary solution representations are susceptible to a loss of diversity and poor scalability. To address those issues, we propose to use artificial neural networks for generating solutions by performing a binary classification of items using the information about their profits and weights. As gradient-based learning cannot be used when target values are unknown, neuroevolution is adapted to adjust the neural network parameters. The main contribution of this study resides in developing a solution encoding and genotype-phenotype mapping for EMOAs to solve MOKPs. The proposal is implemented within a state-of-the-art EMOA and benchmarked against traditional variation operators based on binary crossovers. The obtained experimental results indicate a superior performance of the proposed approach. Furthermore, it is advantageous in terms of scalability and can be readily incorporated into different EMOAs.