This paper proposes an asymmetrical pulse-width modulation (PWM) strategy for current-fed dual-active bridge (CFDAB) converters applied to energy storage systems (ESS). The ESS application considers low-voltage and high-capacity batteries, for low-power applications, such as data centers, residential photovoltaic systems (PV), and uninterruptable power supplies (UPS). The proposed modulation permits the use of an isolation transformer with negligible leakage inductance and, therefore, avoids the use of auxiliary circuits such as snubbers, active-clamp, or resonant cells. Hence, the converter implementation is simplified. The modulation also benefits the design of the control system because the converter can be modeled and controlled using simple strategies. A straightforward, large-signal model for the battery charge mode, which is valid over all the operation range of the converter, is obtained. Also, the converter operates with a fixed dc bus voltage on both charge and discharge modes. These characteristics represent a significant advantage when the CFDAB with PWM modulation is compared with phase-shifted or frequency modulations, commonly applied in these converters.