“…Using the following equations, we can estimate φ b ’s at metal/n-type and metal/p-type semiconductor junctions. where n is the diode ideality factor. The difference between the conduction band minimum ( E C ) and E F is 1.33 eV and the difference between E F and the valence band maximum ( E V ) is 0.57 eV for a neutral pentacene. ,,, Therefore, we can determine φ b at our graphene/pentacene junction under a specific V g : 0.74 and 0.97 eV under V g of −2.0 and −1.0 V, respectively, in p-type region; 1.71 and 1.50 eV under V g of 1.0 and 2.0 V, respectively, in n-type region. In p-type region, barrier height for holes (φ b2 ) increases as V g increases from −2.0 to −1.0 V. In n-type region, barrier height for electrons (φ b1 ) decreases as V g increases from 1.0 to 2.0 V. These results demonstrate that E F of graphene is modulated by applied V g leading to ambipolar characteristics of a graphene/pentacene barristor with a tunable φ b .…”