Air pollution, especially the continual increase in atmospheric particulate matter (PM), is a global environmental challenge. To reduce the PM concentration, a remarkable amount of machine learningbased research has been proposed. However, increasing the accuracy of the predictions and providing clear interpretations of the predictions are challenging. In particular, no studies have addressed models that predict and interpret PM before and during the COVID-19 pandemic. In this paper, we present a two-step predictive and explainable model to obtain insights into reducing PM. We first use attentive multi-task learning to predict the air quality of cities. To accurately predict the concentration of particles with sizes of ∼10 µm or ≤2.5 µm (PM 10 and PM 2.5 , respectively), we demonstrate a performance difference between single-task and multi-task learning, as well as among the state-of-the art methods. The proposed attentive model with multi-task learning outperformed the others in terms of accuracy performance. We then used Shapley additive explanations, a representative explainable artificial intelligence framework, to interpret and determine the significance of features for predicting PM 10 and PM 2.5 . We demonstrated the superiority of the proposed approach in predicting and explaining both PM 10 and PM 2.5 concentrations, and observed a statistically significant difference in air pollution before and during the COVID-19 pandemic.