“…The structures of hydrated oxide films are known to be affected by relative humidity [47] and by alloy composition [48], and there could be phase changes at particular levels of relative humidity, composition, and temperature. (A change in colour of the oxide film of AA7022-T651 alloy in distilled water over a narrow temperature range around 40 • C has been observed, suggesting that phase changes do occur [18].)…”
Section: The Effect Of Environment On the Scc Velocity In The Peak-agmentioning
“…The structures of hydrated oxide films are known to be affected by relative humidity [47] and by alloy composition [48], and there could be phase changes at particular levels of relative humidity, composition, and temperature. (A change in colour of the oxide film of AA7022-T651 alloy in distilled water over a narrow temperature range around 40 • C has been observed, suggesting that phase changes do occur [18].)…”
Section: The Effect Of Environment On the Scc Velocity In The Peak-agmentioning
“…7b) is specified as the bending modes of hydroxyl groups in alcohol, water and Al-OH-Al groups [40], and is recognized as a characteristic of boehmite or pseudo-boehmite [43]. Moreover, the small shoulder at 3100 cm −1 indicates the appearance of boehmite [40].…”
“…Alwitt [5] demonstrated that such a pseudoBoehmite layer is produced on pure aluminum when it is immersed in pure water at or above 50 1C. Inspired by this information, further work has shown that a porous hydrated oxide structure can be obtained on the bare aluminum alloy 2024 T3 and the clad alloy, 7075 T6 at water temperatures as low as 40 1C [6]. When warm water pretreatment at either 40 or 50 1C has been used on these alloys, adhesive joints that give excellent performance in the wedge test have been produced [7].…”
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