1996
DOI: 10.1016/s0268-005x(96)80048-8
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Hydration characteristics of the gum exudate from Acacia senegal

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Cited by 40 publications
(18 citation statements)
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“…We remember that the "hydration number (n h )" refers to water molecules involved in the hydration shell, and then with significant perturbation of its physicochemical properties. These values are in the range of the 0.6-1.2 g H 2 O•g −1 values of interacting "bound" water experimentally measured on Acacia senegal gum by water adsorption experiments or DSC [4,123,126], validating a posteriori the approximations we used for calculations. More specifically, values around 0.6-0.7 g H 2 O•g −1 were found for raw A. senegal gum and values around 0.9-1.2 g H 2 O•g −1 were found for calcium or sodium salts of the gum, showing the role of minerals on molecule hydration.…”
Section: Additional Comments On the Hydration Properties Of Agpssupporting
confidence: 64%
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“…We remember that the "hydration number (n h )" refers to water molecules involved in the hydration shell, and then with significant perturbation of its physicochemical properties. These values are in the range of the 0.6-1.2 g H 2 O•g −1 values of interacting "bound" water experimentally measured on Acacia senegal gum by water adsorption experiments or DSC [4,123,126], validating a posteriori the approximations we used for calculations. More specifically, values around 0.6-0.7 g H 2 O•g −1 were found for raw A. senegal gum and values around 0.9-1.2 g H 2 O•g −1 were found for calcium or sodium salts of the gum, showing the role of minerals on molecule hydration.…”
Section: Additional Comments On the Hydration Properties Of Agpssupporting
confidence: 64%
“…Interestingly, like phytoglycogen, hyperbranched AGPs from Acacia gums may adsorb a maximum amount of 3-4 g H 2 O•g −1 AGP, as determined from DSC experiments. This also indicated the formation of a three-dimensional network of AGP and water builds up as a structured entity [123]. We are then faced to an apparent contradiction, since sugars in AGPs displayed the same behavior than single sugars in solution, but a network of interacting water molecules seems to be created.…”
Section: Additional Comments On the Hydration Properties Of Agpsmentioning
confidence: 99%
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“…The model also shows two shallow pockets in AHP-1, the first lined by Gal, GlcUA, and Rha and the second by side chain Gal residue G a and main chain Gal residues G 1-3 . The main chain Gal residues G 0 , G 1 , and G 2 each have a 1,6-linked side chain substituent in close proximity to one another; this results in steric hindrance to their rotation around the 1,6-linkage, further enhanced by the H-bonding, and thus may also stabilize these shallow pockets as putative water-binding sites that may account for the nonfreezing water content identified by differential scanning calorimetry of gum arabic arabinogalactan polysaccharides (43).…”
Section: A Molecular Model Of Ahp-1mentioning
confidence: 99%