Hydrazone-derived copper(II) coordination polymer as a selective liquid-phase catalyst: Synthesis, crystal structure and performance towards benzyl alcohol oxidation

Copper-complexed dipyridyl-pyridazine functionalized periodic mesoporous organosilica as a heterogeneous catalyst for styrene epoxidation

“…This latter could also be formed by the direct oxidation of BO with TBHP. 51,52 Furthermore, the oxidation of styrene to acetophenone (AP), also detected as the reaction product, proceeds via the formation of intermediate peroxo metallocycle species (V) by the interaction of the peroxo group with the double bonds of the styrene molecules (Path 2).…”

Polyamide nanocomposites containing hydrazide–hydrazone group reinforced with functionalized polyethyleneimine modified Mg(OH)2 nanoparticles: Study on thermal properties, combustion resistance, and lead ion adsorption

“…Absorption band intensities were reported as (w) for weak, (m) for medium, (sh) for shoulder, (s) for strong, and (br) for broad. The 1 H and 13 C NMR spectra were done in DMSO-d 6 by Bruker 300 MHz instrument made in Germany. By using a vario EL cube Elemental Analyzer measured the carbon, hydrogen, and nitrogen percent's of the synthesized PA.…”

“…[11] Therefore, synthetic polymers containing amide, amine, azomethine, hydrazone, and hydrazide-hydrazone as the polymeric matrix can be promising materials for synthesizing polymer nanocomposites for the creation complex and adsorption of the heavy metal ions. [12][13][14][15][16] Aromatic polyamide (aramide), as high-performance materials, utilized in various application fields, such as building, consumer goods, automobiles, electronics, and packaging. [17][18][19] However, many of them have low solubility and thermal stability, which limited their performance in various applications.…”

Rapid Catalysis for Aerobic Oxidation of Alcohols Based on Nitroxyl-Radical-Free Copper(II) under Ambient Conditions

“…The Cu/TEMPO catalytic mechanism showed that copper­(II) with N 4 or N 2 O 2 chelates indicated excellent catalytic activity for selective oxidation of alcohols. , Interestingly, Schiff base ligands were the type of tetradentate ligands with four donor sites of N 2 O 2 . A series of Schiff base complexes, such as Cu, Mn, Fe, Co, and Zn, have been synthesized for the catalysis of alcohol oxidation. − A metal Schiff base catalyst has high catalytic activity, whereas the selectivity of aldehydes is lower. The possible reason is that the Schiff base ligand is not involved in the catalytic effect.…”