Hydroalkylation of terminal aryl alkynes with alkyl diacyl peroxides

Stereoselective Rhodium-Catalyzed Isomerization of Stereoisomeric Mixtures of Arylalkenes

“…19 (E)-2- (But-1-en-1-yl) These spectroscopic data match those previously reported. 21 Prop-1-ene-1,3-diyldibenzene (E-1v) Colorless oil; yield: 52.9 mg (91%); E/Z = 11:1. These spectroscopic data match those previously reported.…”

Recent Progress on Radical Decarboxylative Alkylation for Csp3–C Bond Formation

“…52 In 2016, the Bao group turned its attention to the study of new reaction mechanisms and new applications of alkyl diacyl peroxides. [53][54][55][56]58,59 Significant progress has been achieved based on the discovery of the inherent functionalities of alkyl diacyl peroxides as alkyl resources and oxidants. The Zhu and the Yu groups have also contributed their efforts to studies in this area.…”

“…In 2016, the Bao group used alkyl diacyl peroxides for the hydroalkylation of terminal arylalkynes to produce Zselective alkenes under photo and nickel co-catalysis (Scheme 41). 54 Alkyl diacyl peroxides acted as the alkylat-…”

Photoredox‐ and Nickel‐Catalyzed Hydroalkylation of Alkynes with 4‐Alkyl‐1,4‐dihydropyridines: Ligand‐Controlled Regioselectivity

“…Functionalized alkenes are versatile synthetic intermediates found in various useful molecules and materials [1] . Among the vast range of methods to prepare functionalized alkenes, [2,3] hydroalkylation of alkynes [4–7] has been gaining attention as a convenient synthetic method to prepare functionalized alkenes with Markovnikov [8–11] or anti ‐Markovnikov [12–17] selectivity. In addition, functionalization of alkynes has been recently expanded by the introduction of visible light‐triggered generation of carbon‐centered radicals through a single electron transfer (SET) processes mediated by photoredox catalysts; [18] this has also been applied to the hydroalkylation of alkynes to form functionalized alkenes [6,7,9–11,13–17,19] .…”