1991
DOI: 10.1016/0926-860x(91)85003-g
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Hydrocarbons conversions over Y-zeolite used in uranium ore wastes treatment Activity and selectivity of Y-faujasite modified by uranyl ions in the catalytic disproportionation of toluene

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Cited by 6 publications
(6 citation statements)
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“…The general composition of zeolites can be represented by M y/z [(SiO 2 ) x (AlO 2 ) y ]nH 2 O where M is the exchangeable ion metal with a valency z. Zeolites are a suitable choice as they have a large cation exchange capacity and an affinity for heavy metals [4][5][6][7][8][9]. They are widely used as sorbents [10][11][12][13][14], catalysts [15][16][17][18] and cation exchangers [19][20][21][22][23]. The NaX zeolite cations are located in the sodalite super cage and double hexagonal rings of the zeolite Taking into consideration these approaches, we focus our attention to the use of models based on Fick's laws in the analysis of experimentally obtained data, and to determine the step describing the mechanism of the reaction according to Eq.…”
Section: Introductionmentioning
confidence: 99%
“…The general composition of zeolites can be represented by M y/z [(SiO 2 ) x (AlO 2 ) y ]nH 2 O where M is the exchangeable ion metal with a valency z. Zeolites are a suitable choice as they have a large cation exchange capacity and an affinity for heavy metals [4][5][6][7][8][9]. They are widely used as sorbents [10][11][12][13][14], catalysts [15][16][17][18] and cation exchangers [19][20][21][22][23]. The NaX zeolite cations are located in the sodalite super cage and double hexagonal rings of the zeolite Taking into consideration these approaches, we focus our attention to the use of models based on Fick's laws in the analysis of experimentally obtained data, and to determine the step describing the mechanism of the reaction according to Eq.…”
Section: Introductionmentioning
confidence: 99%
“…Comme les zé olithes, les argiles é changé es pré sentent une acidité de surface comportant des centres acides de types Brö nsted et Lewis et peuvent, par consé quent, avoir une activité catalytique appré ciable dans certaines ré actions chimiques organiques [4,5]. L'introduction de cations bivalent et trivalent dans une structure zé olithique de type Y a pour effet de promouvoir les proprié té s catalytiques de ce maté riau [6][7][8][9]. Des é tudes ulté rieures ont permis d'entrevoir le même effet sur des argiles de type bentonite [10,11].…”
Section: +unclassified
“…On admet gé né ralement que la conversion catalytique du toluè ne dé coule selon un mé canisme ionique [6,8]. Celui-ci fait intervenir l'attaque d'un carbocation sur le cycle aromatique.…”
Section: +unclassified
“…La nature du cation é changé a une influence considé rable sur l'activité . Selon la litté rature [16][17][18], l'activité catalytique de catalyseurs à base de zé olithes varie selon la nature de l'é lé ment introduit comme suit :…”
Section: Introductionunclassified
“…Trois faujasites synthé tiques NaY 1 , NaY 2 et NaY 3 de diffé rents rapports Si/Al ont é té utilisé es. Ces zé olithes ont fait l'objet de caracté risation par diffé rentes techniques dans des travaux anté rieurs [16][17].…”
Section: Introductionunclassified