“…Moreover, the great amount of volatile matter released by the feedstock particles within the bed evolve in the form of so-called endogenous bubbles, which further enhance the segregation of the feedstock [14][15][16][17][18]. As a consequence of segregation, both solid and gas phases cannot take advantage of the enhanced bed-to-fuel transfer phenomena intrinsic of the fluidized-bed technology, which are essential for high product yield and quality [19,20]. All these aspects are essential to the design of industrial fluidized-bed units and relevant to all thermochemical conversion processes, since the evolution of volatiles is common to pyrolysis, gasification and combustion operations.…”