Hydroesterification of methyl 10-undecenoate in thermomorphic multicomponent solvent systems—Process development for the synthesis of sustainable polymer precursors

Kinetic Modeling of the Palladium‐Catalyzed Isomerizing Methoxycarbonylation of 1‐Decene

“…). For all reaction conditions a constant l / b ratio of 94/6 was determined according to the literature , , , . A comparison of concentration profiles for different CO pressures indicated an inhibition of the isomerization with increasing CO pressure.…”

“…Unsaturated oleochemicals from renewables like glycerides, methyl oleate and methyl 10‐undecenoate (UME) have also been proven to be attractive substitutes for petrochemical substrates in the palladium‐catalyzed methoxycarbonylation producing α , ω ‐functionalized intermediates for the production of polyesters and polyamides . For a sustainable and economic catalytic process, the reuse of the catalyst plays a key role.…”

“…For a sustainable and economic catalytic process, the reuse of the catalyst plays a key role. In this context, Gaide et al , successfully demonstrated the Pd/DTBPMB‐catalyzed methoxycarbonylation of UME with high yields of the desired diester using a thermomorphic solvent system (TMS) to recycle the homogeneous catalyst. Thus, a temperature‐dependent miscibility gap enables phase separation at low temperature and an efficient reaction without mass transport limitations at elevated temperature .…”

“…1-Decene was used as model substrate for long chain unsaturated oleochemicals. The composition of the TMS and the highly active and selective catalytic system refers to reported results of Gaide et al [6,7]. system, temperature controller and pressure regulator.…”

From Carboxytelomerization of 1,3‐Butadiene to Linear α,ω‐C10‐Diester Combinatoric Approaches for an Efficient Synthetic Route

“…Here, the ligand 1,2-di-tertbutylphosphinomethyl)benzene 1,2-DTBPMB plays ak ey role to achieveh igh selectivities towards the desired linear C 10 -diester 3. [30] The chemicalr eaction equation of the methoxycarbonylation of methyl 10-undecenoate 4 is illustrated in Scheme 3.…”