Hydroesterification of tert-butyl alcohol in room temperature ionic liquids

Imidazolium Ionic Liquids: An Environment-Friendly Medium for Various Applications

“…The Beckmann rearrangement of cyclo-hexanone oxime in IL [Bmim]BF 4 has been described [134][135][136]. K. Qiao et al [137] described the synthesis of ethyl iso-valerate and ethyl tertvalerate Pd(PPh 3 ) 2 Cl 2 catalyst for hydroesterification of tert-butyl alcohol using IL. A new, base-stable, imidazolium IL has been used for the addition of Grignard reagents [138] to carbonyl compounds.…”

Palladium-catalyzed hydroesterification of styrene derivatives in the presence of ionic liquids

“…The palladium-catalyzed hydroesterification of styrene and other derivatives in a biphasic IL medium composed of 1-butyl-3-methylimidazolium tetrafluoroborate ([C 4 mim][BF 4 ]), isopropanol, and cyclohexane has been previously reported [19]; however, [C 4 mim] [BF 4 ] was the only IL studied and recycling of the catalyst was not achieved. Additionally, the palladium-catalyzed hydroesterification of aryl halides and tert-butyl alcohol in ILs to give the corresponding esters has been reported [20,21]. Our group, and others, recently reported the palladium-catalyzed co-polymerization of styrene and CO in ILs [22][23][24] where the polymerization occurs with catalysts supported by chelating ligands.…”

Palladium‐Catalyzed Carbonylation of sec‐ and tert‐Alcohols

“…[16] Ag eneral problem of such reactions is the formation of the corresponding ether from the alcohol. [16] Ag eneral problem of such reactions is the formation of the corresponding ether from the alcohol.…”