2013
DOI: 10.1590/s1516-14392013005000049
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Hydrogen absorption study of ti-based alloys performed by melt-spinning

Abstract: The hydrogen absorption and desorption of Ti 53 Zr 27 Ni 20 icosahedral quasicrystal (ICQ) and Ti 50 Ni 50 shape memory alloy (SMA) melt-spun ribbons was studied. Samples were exposed to hydrogen gas at 623 K and 4 MPa for 1000 minutes. The total capacity of hydrogen obtained for Ti 53 Zr 27 Ni 20 and Ti 50 Ni 50 was 3.2 and 2.4 wt. % respectively. The Thermal Desorption Spectrometry (TDS) of the hydrogenated alloys shows that both alloys start to desorb hydrogen around 750 K. X-ray diffraction (XRD) patterns,… Show more

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Cited by 17 publications
(7 citation statements)
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“…The VA2/VA3/VA4 treatments involved annealing for respectively 8/16/34 h at 950 K under P ~ 10 −3 Pa. The annealing temperatures were chosen to be higher than the temperature ranges of hydrogen desorption from Ni-Ti alloys reported in the literature [ 17 , 18 , 19 ].…”
Section: Methodsmentioning
confidence: 99%
“…The VA2/VA3/VA4 treatments involved annealing for respectively 8/16/34 h at 950 K under P ~ 10 −3 Pa. The annealing temperatures were chosen to be higher than the temperature ranges of hydrogen desorption from Ni-Ti alloys reported in the literature [ 17 , 18 , 19 ].…”
Section: Methodsmentioning
confidence: 99%
“…The VA treatment consisted in annealing for 26 h at 950 K under a residual gas pressure P ≈ 10 −3 Pa. The annealing temperature was chosen to be higher than the temperature ranges of hydrogen desorption from Ni-Ti alloys reported in the literature [16][17][18]. Two samples were used for acoustic measurements: one after only the WQ treatment and another one subjected to a combination of the WQ and VA treatments.…”
Section: Methodsmentioning
confidence: 99%
“…A marked kinetic improvement achieved by alloying with Ni was demonstrated for TieNi-based alloys, which can absorb a considerable amount of hydrogen at a high temperature of 623 K and a pressure of 4 MPa. TieNi has the AB 2 composition; however, similar to other light metal-based materials, the use of catalysts can improve the undesirable or slow kinetic properties [110,111]. These problems should be overcome for the practical use of this material for hydrogen storage applications [110].…”
Section: Alloyingmentioning
confidence: 99%