Formation of negative hydrogen ion: Polarization electron capture and nonthermal shielding J. Chem. Phys. 137, 094310 (2012) Ionization energy of atoms obtained from GW self-energy or from random phase approximation total energies J. Chem. Phys. 136, 194107 (2012) Scattering of nitrogen molecules by silver atoms J. Chem. Phys. 136, 164305 (2012) Rotational excitation of H2O by para-H2 from an adiabatically reduced dimensional potential J. Chem. Phys. 136, 094109 (2012) Additional information on Rev. Sci. Instrum. Positive and negative hydrogen ions are produced by plasma-assisted catalytic ionization using a porous nickel plate, where the irradiation current density and energy of positive ions produced by discharge to the porous plate are controlled. The ion energy distributions are analyzed from the properties of current densities of positive and negative ions extracted from the porous surface. Positive ions passing through fine pores of the porous plate and positive and negative ions produced on the porous surface are observed. It is clarified that the produced fluxes of positive and negative ions and the flux balance between them are controlled by the irradiation current density and energy, respectively.