Hydrogen-Bonded Organic Frameworks for Antibiotic Fluorescent Sensing Artificial Intelligence-Enhanced Anticounterfeiting

Abstract

The paramount importance of anticounterfeiting measures in safeguarding consumers from counterfeit products lies in their ability to ensure product safety and reliability. Advanced luminescent anticounterfeiting materials, particularly those responsive to multiple stimuli, afford a dynamic and multilayered security assurance. This study presents the synthesis of a novel material, Eu/Tb@GC-3, via postsynthetic modification, which exhibits notable photoluminescent properties with emission at 544 and 614 nm. The material demonstrates high selectivity and sensitivity in detecting Nitrofural and Enrofloxacin, with limits of detection at 0.0122 and 0.0280 μM, respectively. Furthermore, multistimulus responsive luminescent fibers and inks were developed, facilitating intelligent anticounterfeiting labels. The integration of these labels with back-propagation neural networks (BPNNs) significantly enhances pattern recognition and authentication capabilities, providing an efficacious strategy to combat counterfeit products and ensure consumer safety.