Hydrogen-bonding directed cocrystallization of flexible piperazine with hydroxybenzoic acid derivatives: Structural diversity and synthon prediction

Wang, Lei; Xue, RuiFeng; Xu, Lingyan; Lu, Xifeng; Chen, Ruixin; Tao, Xutang

doi:10.1007/s11426-011-4487-4

Cited by 13 publications

(4 citation statements)

References 28 publications

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“…( PAD )S=O⋅⋅⋅H−N (amino acid), ( PANP )N−H⋅⋅⋅O(amino acid)). In addition, N atoms also contribute forming strong N⋅⋅⋅H−O interactions . Furthermore, detailed observation of the friction ridge features (see enlarged areas in Figure ), showed whorl, bifurcation, and ridge ending, which satisfy to a large extend the requirements of fingerprint identification.…”

Section: Methodsmentioning

confidence: 81%

“…The longer temporal stability observedf or PAD and PANP was ascribed to their respective structural outfit bearing functional groups capable of providing hydrogen-bonding with the residual aminoa cids in the fingerprints( e.g. [14,[50][51][52][53][54] Furthermore, detailedo bservation of the friction ridge features (see enlarged areas in Figure2), showed whorl, bifurcation, and ridge ending, which satisfyt oalarge extendt he requirements of fingerprint identification.I nterestingly,o ur fingerprint development process also offered distinguished visual legibility on other surfaces, including handset phones urfaces ( Figure S15).…”

mentioning

confidence: 99%

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Fluorescent‐Labeled Octasilsesquioxane Nanohybrids as Potential Materials for Latent Fingerprinting Detection

Dare

Vendrell-Criado

Jiménez

et al. 2020

Chemistry A European J

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The recent demand for fluorescent‐labeled materials (FLMs) in forensic security concepts such as latent fingerprints (LFs) that encode information for anti‐counterfeiting and encryption of confidential data makes necessary the development of building new and innovative materials. Here, novel FLMs based on polyhedral oligomeric silsesquioxanes (POSS) functionalized with fluorophores via “click” reactions have been successfully synthesized and fully characterized. A comprehensive study of their photophysical properties has displayed large Stokes's shift together with good photostability in all cases, fulfilling the fundamental requisites for any legible LF detection on various surfaces. The excellent performance of the hetero‐bifunctional FLM in the visualization of LF is emphasized by their legibility, selectivity, sensitivity and temporal photostability. In this study, development mechanisms have been proposed and the overall concept constitute a novel approach for vis‐à‐vis forensic investigations to trace an individual's identity.

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Section: Methodsmentioning

confidence: 81%

mentioning

confidence: 99%

Fluorescent‐Labeled Octasilsesquioxane Nanohybrids as Potential Materials for Latent Fingerprinting Detection

Dare

Vendrell-Criado

Jiménez

et al. 2020

Chemistry A European J

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“…According to the WHO model list of essential medicines, GCZ is one of the most remarkable medications needed in the basic health system . Use of high soluble coformers can heighten solubility. , Piperazine is distinctive as a coformer for cocrystallization or salt formation . Phenolic coformers play a ubiquitous role in authenticating solubility advantages .…”

Section: Introductionmentioning

confidence: 99%

“…18,26 Piperazine is distinctive as a coformer for cocrystallization or salt formation. 27 Phenolic coformers play a ubiquitous role in authenticating solubility advantages. 28 There is no report for either TOL or GPZ salts/cocrystals nor even a report for the crystal structure determination of pure GPZ.…”

Section: ■ Introductionmentioning

confidence: 99%

Salts and Cocrystals of the Antidiabetic Drugs Gliclazide, Tolbutamide, and Glipizide: Solubility Enhancements through Drug–Coformer Interactions

Samie

Desiraju

Banik

2017

Crystal Growth & Design

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Gliclazide (GCZ), tolbutamide (TOL), and glipizide (GPZ) are BCS class II antidiabetic drugs with poor aqueous solubility. Multicomponent solid forms, salts, and cocrystals of GCZ were obtained upon liquid assisted grinding with coformers of catechol, resorcinol, p-toluenesulfonic acid, and piperazine. The solubility of TOL was also modified by salt formation with piperazine (PPZ). The multicomponent solids were characterized by single crystal X-ray diffraction, powder X-ray diffraction, Fourier transform infrared spectroscopy, differential scanning calorimetry, and thermal gravimetric analysis and further subjected to solubility studies. The cocrystals/salts, in all cases, showed improvements in the solubility and dissolution rates compared to the parent active pharmaceutical ingredients. GCZ–PPZ and TOL–PPZ(I) showed 6.6 and 80 and fold enhancements respectively in the solubility. The reasons for the improved solubility of the cocrystals/salts in terms of drug–coformer interactions are discussed.

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Three-dimensional supramolecular architecture based on 4,4′-methylene-bis(benzenamine) and aromatic carboxylic acid guests: Synthons cooperation, robust motifs and structural diversity

et al. 2012

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Hydrogen-bonding directed cocrystallization of flexible piperazine with hydroxybenzoic acid derivatives: Structural diversity and synthon prediction

Cited by 13 publications

References 28 publications

Fluorescent‐Labeled Octasilsesquioxane Nanohybrids as Potential Materials for Latent Fingerprinting Detection

Fluorescent‐Labeled Octasilsesquioxane Nanohybrids as Potential Materials for Latent Fingerprinting Detection

Salts and Cocrystals of the Antidiabetic Drugs Gliclazide, Tolbutamide, and Glipizide: Solubility Enhancements through Drug–Coformer Interactions

Three-dimensional supramolecular architecture based on 4,4′-methylene-bis(benzenamine) and aromatic carboxylic acid guests: Synthons cooperation, robust motifs and structural diversity

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