“…Similarly, the H---S distances (RT) of 2.284 (11) and 2.340 (115 A and (LT) of 2.268 (105 and 2.291 (8) A are considerably smaller than the radii sum of r, + r s = 2.80 ~ according to ~be values r, = 1.0 A (Baur, 1972) and r s = 1.80 A. The O-H...S hydrogen bonds are therefore stronger than those observed in Schlippe's salt Na3SbS4.9H20 (Mereiter, Preisinger & Guth, 1979) where H...S distances in the range from 2.343 and 2.407 A were found. A shorter H...S distance was observed by Van Roey & Kerr (1981) Introduction.…”
Section: K 120 Kmentioning
confidence: 75%
“…H20 (Manojlovi+-Muir, 1975) and (NH4)2S203 (Teng, Fuess & Bats, 1979), where values of 1.979 (3) Only very few neutron diffraction studies of O-H...S bonds are reported in the literature (Mereiter, Preisinger & Guth. 1979" Van Roev & Kerr, 1981.…”
Section: K 120 Kmentioning
confidence: 99%
“…All of them show O-H...S bonds which are almost linear with deviations between 2 and 15 ° from linearity. An average value of 3.32 A for the oxygensulphur distance is given from several X-ray studies (Mereiter et al, 1979).…”
Abstract. MgS20 3. 6H20, orthorhombic, Pnma, Z = 4, a = 9.405 (4), b = 14.449 (4), c = 6.866 (4) A, V = 933.0 A 3 (at 296 K) and a = 9.304 (3), b = 14.447 (3), c = 6.847, V = 920.3 A 3 (at 120 K).
“…Similarly, the H---S distances (RT) of 2.284 (11) and 2.340 (115 A and (LT) of 2.268 (105 and 2.291 (8) A are considerably smaller than the radii sum of r, + r s = 2.80 ~ according to ~be values r, = 1.0 A (Baur, 1972) and r s = 1.80 A. The O-H...S hydrogen bonds are therefore stronger than those observed in Schlippe's salt Na3SbS4.9H20 (Mereiter, Preisinger & Guth, 1979) where H...S distances in the range from 2.343 and 2.407 A were found. A shorter H...S distance was observed by Van Roey & Kerr (1981) Introduction.…”
Section: K 120 Kmentioning
confidence: 75%
“…H20 (Manojlovi+-Muir, 1975) and (NH4)2S203 (Teng, Fuess & Bats, 1979), where values of 1.979 (3) Only very few neutron diffraction studies of O-H...S bonds are reported in the literature (Mereiter, Preisinger & Guth. 1979" Van Roev & Kerr, 1981.…”
Section: K 120 Kmentioning
confidence: 99%
“…All of them show O-H...S bonds which are almost linear with deviations between 2 and 15 ° from linearity. An average value of 3.32 A for the oxygensulphur distance is given from several X-ray studies (Mereiter et al, 1979).…”
Abstract. MgS20 3. 6H20, orthorhombic, Pnma, Z = 4, a = 9.405 (4), b = 14.449 (4), c = 6.866 (4) A, V = 933.0 A 3 (at 296 K) and a = 9.304 (3), b = 14.447 (3), c = 6.847, V = 920.3 A 3 (at 120 K).
“…2). Das gleiche gilt für mögliche OH -S-Brücken (O w -SAbstände > 3,6 A), obwohl zumindestens der klei nere der infrage kom m enden H -S-Abstände ( H l -S: 2,81(5)Ä) nach [13] …”
Section: Strukturbeschreibung Und Diskussionunclassified
“…Lithium coordinates four water O atoms forming a distorted tetrahedron. Such tetrahedra, related via a centre of inversion, are kept together in pairs by two equivalent 0(4)... H 1 (03)-0(3) hydrogen bonds (Hamilton & Ibers, 1968) Mereiter, Preisinger & Guth (1979). The dithiocarbamate ions are van der Waals packed antiparallel to each other in the channel formed by four chains of Li tetrahedra.…”
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.