Hydrogen Bonds Involving the C-H←F Link. XII¹

Kinetic study of the synthesis of a methacrylic ester copolymer by nuclear magnetic resonance

“…A good agreement is observed with first-order reaction kinetics. 11 In general, the initiator concentration does not change during the polymerization. When the initiator efficiency does not depend on its concentration, a first-order behavior is expected for the reaction kinetics, as observed for the MMA-AIBN system.…”

Synthesis of a polymer chain having conjugated unsaturated bonds by dehydrohalogenation of polyhalogen‐containing polymers

“…The resultant degraded polymer exhibits reaction typical of an organic unsaturated material, which is considered to have resulted, for the most part, from the removal of chlorine in combination with hydrogen from an adjacent carbon as shown in eq. (1). CHz…”

Kinetics of the photopolymerization of tetraethylene glycol dimethacrylate in the bulk with the use of desyl aryl sulfides as photoinitiators

“…' Likewise, thr 1)rnmyl peroxide-initiat,ctl polymerization of d-sec-butyl a-chloroacrylate and vinyl I-B-phenylbutyrate in dioxane are quite accurately first-order up to high conversion. 2 It is also known that the polymerization of certain monomers in the bulk or in concentrated solutions is accompanied by a marked deviation from first-order kinetics in the direction of an increase in the reaction rate termed autoacceleration. This effect is particularly pronounced with the benzoyl peroxide-initiated polymerization of methyl methacrylate3 and with the photo-initiated polymerization of methyl methacrylate with benzoin or 2,2'-azobisisobutyronitrile.…”

“…The constants in eq. (1) may be combined to give: R, = k[M][C]0*5 (2) where k represents the overall observed rate constant.…”