2006
DOI: 10.1016/j.jelechem.2006.06.006
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Hydrogen diffusion through the steel membrane in conditions of its anodic polarization

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Cited by 6 publications
(10 citation statements)
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“…The second type is sometimes considered as due to the direct absorption as it "undergoes direct interfacial transfer to a subsurface site, followed by transfer to an interstice below the second surface monolayer becoming absorbed H" [28,29]. However, this view is only valid for monocrystals.…”
Section: Discussionmentioning
confidence: 99%
“…The second type is sometimes considered as due to the direct absorption as it "undergoes direct interfacial transfer to a subsurface site, followed by transfer to an interstice below the second surface monolayer becoming absorbed H" [28,29]. However, this view is only valid for monocrystals.…”
Section: Discussionmentioning
confidence: 99%
“…The exit side of the membrane contacted with a titrated permanganate solution, which completely oxidized hydrogen diffused across the membrane. The hydrogen diffusion flux (ί H ) was estimated from the decrease in permanganate concentration [31,32]. The measurements were conducted at the corrosion potential and under cathodic and anodic polarization of the entrance membrane side.…”
Section: Electrochemical Diffusion Methods For the Estimation Of Hydromentioning
confidence: 99%
“…The presence of a maximum on the i H = f (∆E a ) plot was observed by many researches [33][34][35][36]. The explanation of the validity of its presence has been made a few years ago in [32].…”
Section: Hydrogen Diffusion Flux At Anodic Polarization Of the Membramentioning
confidence: 98%
“…It is even more difficult to interpret the situation when, as the experimental data [1][2][3][4] have demonstrated, a number of parameters of the process in different solvents is the same, whereas in their mixtures it is basically different. In our opinion, this change is stipulated by the fact that every system, even of the simplest binary composition, X Solvent 1 þ ð1 À XÞ Solvent 2 ;…”
Section: Introductionmentioning
confidence: 99%