Hydrogen generation using sodium borohydride solution and metal catalyst coated on metal oxide

Kojima, Yoshiyuki; Suzuki, Kyohei; Fukumoto, Kazuhiro; Sasaki, Megumi; Yamamoto, Takahisa; Kawai, Yasuhiko; Hayashi, Hiroaki

doi:10.1016/s0360-3199(02)00014-9

Cited by 533 publications

(310 citation statements)

References 10 publications

Supporting

Mentioning

299

Contrasting

Order By: Relevance

“…[11] In the absence of an alkaline solution, NaBH 4 spontaneously reacts with water. [23] The hydrolysis of NaBH 4 can effectively liberate hydrogen at room temperature in the presence of a catalyst via the following reaction [Equation (1)]: [10,12,22,[24][25][26] …”

Section: Catalytic Hydrolysis Of Sodium and Lithium Borohydridesmentioning

confidence: 99%

“…It is reported that 4 equivalents of hydrogen can be completely generated in 16 min in the presence of 1.5 wt % Pt-LiCoO 2 , one of the most active catalysts for this reaction (molar ratio: Pt/NaBH 4 = 0.0002). [26] For Pt-based catalysts, the catalytic activity was increased by decreasing the Pt particle size. [26,29] Palladium supported on carbon powder (Pd/C) and palladium in the forms of Pd and PdÀC thin films synthesized by pulsed laser deposition (PLD) were also employed to study the hydrogen generation by the catalytic hydrolysis of an alkaline NaBH 4 solution.…”

Section: Catalytic Hydrolysis Of Sodium and Lithium Borohydridesmentioning

confidence: 99%

See 1 more Smart Citation

Liquid‐Phase Chemical Hydrogen Storage: Catalytic Hydrogen Generation under Ambient Conditions

et al. 2010

View full text Add to dashboard Cite

There is a demand for a sufficient and sustainable energy supply. Hence, the search for applicable hydrogen storage materials is extremely important owing to the diversified merits of hydrogen energy. Lithium and sodium borohydride, ammonia borane, hydrazine, and formic acid have been extensively investigated as promising hydrogen storage materials based on their relatively high hydrogen content. Significant advances, such as hydrogen generation temperatures and reaction kinetics, have been made in the catalytic hydrolysis of aqueous lithium and sodium borohydride and ammonia borane as well as in the catalytic decomposition of hydrous hydrazine and formic acid. In this Minireview we briefly survey the research progresses in catalytic hydrogen generation from these liquid-phase chemical hydrogen storage materials.

show abstract

Section: Catalytic Hydrolysis Of Sodium and Lithium Borohydridesmentioning

confidence: 99%

Section: Catalytic Hydrolysis Of Sodium and Lithium Borohydridesmentioning

confidence: 99%

Liquid‐Phase Chemical Hydrogen Storage: Catalytic Hydrogen Generation under Ambient Conditions

et al. 2010

View full text Add to dashboard Cite

show abstract

“…Some precious metals had shown excellent catalytic activities in the hydrolysis of NaBH 4 solution to produce pure hydrogen [2][3][4]. It is obvious that this kind of catalysts is expensive.…”

Section: Introductionmentioning

confidence: 99%

Cobalt boride catalysts for hydrogen generation from alkaline NaBH4 solution

Bai

et al. 2005

Materials Letters

221

View full text Add to dashboard Cite

“…18 In the last years, significant advances were made and prototypes and commercial products emerged. 19−21 The reaction today has a high technological readiness level (TRL); it is between TRL7, i.e.…”

Section: Liquid-state Hydrogen Storagementioning

confidence: 99%

Sodium borohydride for the near-future energy: a ''rough diamond'' for Turkey

Demirci¹

2018

Turk J Chem

View full text Add to dashboard Cite

Boron-based materials are potential solutions in the field of energy. They have been regarded as hydrogen storage materials, liquid fuels of direct liquid-fed fuel cells (DLFCs), electrolytes of battery, and/or energetic substances.A typical example is sodium borohydride (NaBH 4) . In sodium hydroxide-stabilized aqueous solutions, it is seen as an efficient H 2 generator or a performing fuel of DLFCs. Actually, it plays a wider role; it is also the precursor of several boron-based materials of interest in the field of energy. In other words, it is indirectly considered for other energy applications, i.e. solid electrolytes of all solid-state batteries and hypergolic fuel. De facto sodium borohydride has become a key material in the field of energy. This is discussed in the present article, and it is highlighted that sodium borohydride may be clearly seen as a "rough diamond" for Turkey.

show abstract

Hydrogen generation using sodium borohydride solution and metal catalyst coated on metal oxide

Cited by 533 publications

References 10 publications

Liquid‐Phase Chemical Hydrogen Storage: Catalytic Hydrogen Generation under Ambient Conditions

Liquid‐Phase Chemical Hydrogen Storage: Catalytic Hydrogen Generation under Ambient Conditions

Cobalt boride catalysts for hydrogen generation from alkaline NaBH4 solution

Sodium borohydride for the near-future energy: a ''rough diamond'' for Turkey

Contact Info

Product

Resources

About