Hydrogen, as a clean energy carrier, could be produced aided by cyclic oxidation-reduction of oxygen carriers (OCs) in contact with carbonaceous fuel in chemical looping steam methane reforming (CL-SMR) process. In this study, the cerium was incorporated into the SBA-16 support structure to synthesize the Ni/Ce-SBA-16 OC. The supports were synthesized using hydrothermal method followed by impregnation of Ni and characterized via low and wide angle X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), scanning electron microscopy (SEM), coupled with energy dispersive X-ray (EDX) spectroscopy, and transmission electron micrograph (TEM) techniques. In addition, the effect of various Si/Ce molar ratios (20-60) in the support structure, Ni loading (10-30 wt %), reaction temperature (500-750 • C), and life time of optimal oxygen carrier over 16 cycles were investigated. The results of wide angle XRD and SEM revealed that the incorporation of CeO 2 in the channels of SBA-16 caused the formation of nickel metallic particles with smaller size and prevents the coke formation. The results showed that OC with 15 wt % Ni and Si/Ce molar ratio of 40 (15Ni/Ce-SBA-16(40)) has the best performance when compared with other OCs in terms of catalytic activity and structural properties. The methane conversion of about 99.7% was achieved at 700 • C using 15Ni/Ce-SBA-16(40) OC. We anticipate that the strategy can be extended to investigate a variety of novel modified mesoporous silica as the supporting material for the Ni based OCs.