Hydrogenation of C60 on alumina-supported nickel and thermal properties of C60H36

Osaki, Toshihiko; Tanaka, Toŝhiyuki; Tai, Yutaka

doi:10.1039/a900587k

Cited by 24 publications

(14 citation statements)

References 14 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Hydrogenation of C 60 on alumina-supported nickel leads selectively to C 60 H 36 [72]. Degradation products or other hydrofullerenes such as C 60 H 18 or C 60 H 44 were not observed.…”

Section: Reduction With Molecular Hydrogenmentioning

confidence: 92%

Hydrogenation

2004

Fullerenes

View full text Add to dashboard Cite

“…Hydrogenation of C 60 on alumina-supported nickel leads selectively to C 60 H 36 [72]. Degradation products or other hydrofullerenes such as C 60 H 18 or C 60 H 44 were not observed.…”

Section: Reduction With Molecular Hydrogenmentioning

confidence: 92%

Hydrogenation

2004

Fullerenes

View full text Add to dashboard Cite

“…134 A Ni/Al 2 O 3 catalyst has been used to hydrogenate [60]fullerene under a H 2 atmosphere resulting in the formation of C 60 H 36 . 135 The electrochemistry of C 60 H 36 has been studied and a reversible one-electron reduction forming a radical anion observed. 136 The hydrogenation of the simplest fulleroid, C 61 H 2 , yielding two isomers of C 61 H 4 has been performed using either a Zn/Cu couple or hydroboration.…”

Section: Organic Chemistrymentioning

confidence: 99%

22 Fullerenes

Birkett

2000

Annu. Rep. Prog. Chem., Sect. A

View full text Add to dashboard Cite

“…One of the best methods for the storage of hydrogen is chemical absorption of this gas in other molecules. Fullerene C 60 is proved to be an excellent substrate for absorption of hydrogen by several different methods [44][45][46][47][48][49][50]. Synthesis methods of fullerene hydrides have been extensively developing because these hydrides can have potential applications for hydrogen storage and they have also been suggested as one of the infrared emission sources in interstellar space [51].…”

Section: Introductionmentioning

confidence: 99%

Vibrational Analysis of Fullerene Hydrides Using AIREBO Potential

Golzari

Nejat

2019

Scientia Iranica

View full text Add to dashboard Cite

In this paper, the vibrational properties of fullerene hydrides with the chemical formula C 60 H 2n are investigated using a method based on the potential energy of the molecule. The potential used in this methodology is AIREBO (Adaptive Intermolecular Reactive Empirical Bond Order). Using this interatomic potential, some of the most important frequencies of the fullerene hydrides, such as the breathing mode frequency, were calculated and then analyzed. It was observed that in addition to the number of hydrogen atoms in the structure, their position on the C 60 cage has a significant effect on the natural frequency corresponding to a particular mode shape. The results obtained by this method have been compared and validated with quantum mechanics and experimental observations. The simulations results demonstrate that the proposed method is capable of calculating the vibrational properties of fullerene hydrides with high precision and low computational cost.

show abstract

Hydrogenation of C60 on alumina-supported nickel and thermal properties of C60H36

Cited by 24 publications

References 14 publications

Hydrogenation

Hydrogenation

22 Fullerenes

Vibrational Analysis of Fullerene Hydrides Using AIREBO Potential

Contact Info

Product

Resources

About