Hydrogenation of the "extract'' portion of the lubricant fraction from a midcontinent petroleum

Mair, Beveridge J.; Willingham, Charles B.; Streiff, Anton J.

doi:10.6028/jres.021.031

Cited by 14 publications

(19 citation statements)

References 6 publications

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“…Both Vlugter, Waterman, and Van Westen [5] and Von Fuchs and Anderson [6] have used specific dispersion as a means of obtaining information concerning the chemical constitution of petroleum fractions. The former have used the G and 0 lines, and have pointed out that an oil is practically free from aromatic hydrocarbons when (no-no)/d is less than 158XI0- 4 Mikeska [7] have values for the specific dispersion between 97 and 100 and confirm the observation of Von Fuchs and Anderson. Thirteen of the fifteen fractions prepared by hydrogenation in this investigation [4] had specific dispersion values of 100 or lower.…”

Section: Specific Refractive Dispersion'mentioning

confidence: 75%

“…The former have used the G and 0 lines, and have pointed out that an oil is practically free from aromatic hydrocarbons when (no-no)/d is less than 158XI0- 4 Mikeska [7] have values for the specific dispersion between 97 and 100 and confirm the observation of Von Fuchs and Anderson. Thirteen of the fifteen fractions prepared by hydrogenation in this investigation [4] had specific dispersion values of 100 or lower. Consequently, the straight line drawn at 98.4 in figure 3 represents approximately the specific dispersion values for naphthenes and paraffins.…”

Section: Specific Refractive Dispersion'mentioning

confidence: 75%

“…Five charges, denoted as A, B, 0, D, and E, were prepared from the distillation fractions and each charge was separated into a series of 30 to 40 fractions by extraction with methyl cyanide in 16.7-m (55-ft) columns. The properties of these fractions have been compared with each other and with the properties of 3 fractions from series B, with 10 from series 0, and with 2 from series E, after their complete hydrogenation [4]. They have also been compared with the properties of several series of water-white oil fractions previously prepared by distillation and extraction from the same lubricant fraction [1].…”

Section: Origin Of the Petroleum Fractions And Sources Of The Datmentioning

confidence: 99%

“…The data used for comparison come, for the extract fractions, from tables 9 and 10 of reference [3]; for the hydrogenated fractions, from table 4 of reference [4]; and for the water-white oil fractions, from tables 2 and 3 of reference [1]. …”

Section: Origin Of the Petroleum Fractions And Sources Of The Datmentioning

confidence: 99%

“…3 To obtain a more complete picture of the constitution of the lubricant fraction five series of fractions were prepared in an analogous manner from the extract portion of the same oil and a number of their physical properties determined [3]. Fifteen of these fractions were completely hydrogenated to naphthenes and their physical properties again determined [4]. In this paper data on the extract fractions, the hydrogenated fractions, and the water-white oil are correlated with da t a available in the literature on synthetic hydrocarbons.…”

Section: Introductionmentioning

confidence: 99%

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Chemical constitution of the "extract" portion of the lubricant fraction from a midcontinent petroleum

Mair¹,

Willingham²,

Streiff³

1938

J. RES. NATL. BUR. STAN.

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Section: Specific Refractive Dispersion'mentioning

confidence: 75%

Section: Specific Refractive Dispersion'mentioning

confidence: 75%

Section: Origin Of the Petroleum Fractions And Sources Of The Datmentioning

confidence: 99%

Section: Origin Of the Petroleum Fractions And Sources Of The Datmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 3 more Smart Citations

Chemical constitution of the "extract" portion of the lubricant fraction from a midcontinent petroleum

Mair¹,

Willingham²,

Streiff³

1938

J. RES. NATL. BUR. STAN.

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Use of Inspection Properties to Predict Hydrocarbon Fraction Physical Properties

Nick¹

2000

Encyclopedia of Analytical Chemistry

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The chemical complexity of petroleum products has, until recently, precluded calculational techniques based on a definitive analysis of the molecular species involved. Instead, readily observed or easily (quick and inexpensively) measured macroscopic properties (gravity, boiling range, etc.) have been used to correlate information empirically. In some instances, the predictions have been “tweaked” on a local data‐centric basis or extended by quasi‐theoretical analysis. Recent computer‐aided advancements 134 in multivariate electromagnetic emission, NMR (nuclear magnetic resonance) and/or MS (mass spectroscopy) analyses allow for the reliable and repeatable use of much more detailed experimental data. The ability to speciate cuts by individual chemical components will revolutionize both refining and regulation of refined products in response to the availability of quality data. So why would one bother with older analysis and prediction methods? It is likely, given the operational sophistication and investment costs needed to deliver this highly speciated information properly, that the old ways will die but slowly. Most refineries and petrochemical plants try to get by with the minimum amount of expensive on‐line analyzers. Multivariate data generation is not yet at a state where it can easily be used for real‐time process or even product quality control. This barrier will exist for some time to come. The historical development of crude oil processing technology has generated a great volume of data and “general” correlations, some contradictory. Most of the data upon which these methods are based have been around for 60 or more years. Many have withstood the “test of time”, being examined and verified by numerous researchers both public and private. Some of the precision of the older data may not be as good as what is generated today, but new entries to various refinery products' databanks seem to confirm the validity of the best of the older procedures and data. The classical methods allow one to impute several otherwise unavailable characterizing pieces of data. It is essential that those engaged in the design and analysis of refinery units (which have multiple feed and product streams) become familiar with classical terminology and techniques, and eventually acquire an intuitive sense of what constitutes the “best answer” when confronted with several conflicting alternatives. The subject of this article is the proper methodology of imputing this knowledge from whatever data are at hand.

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Double Bond Index

Lipkin¹,

Martin²

1948

Anal. Chem.

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Hydrogenation of the "extract'' portion of the lubricant fraction from a midcontinent petroleum

Cited by 14 publications

References 6 publications

Chemical constitution of the "extract" portion of the lubricant fraction from a midcontinent petroleum

Chemical constitution of the "extract" portion of the lubricant fraction from a midcontinent petroleum

Use of Inspection Properties to Predict Hydrocarbon Fraction Physical Properties

Double Bond Index

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