In the Upper Kauner Valley of the Tyrolean Central Alps in Austria, some of the slopes, consisting of crystalline bedrock covered by Quaternary deposits, host groundwater of remarkable chemical composition. The bedrock consists mainly of a thick paragneiss series with intercalations of orthogneiss and amphibolite belonging to the Ötztal-Stubai Basement Complex. These metamorphic rocks are ubiquitously fractured and the fracture surfaces are coated with Fe-(hydr-)oxides and chlorite but also carbonates. Sul phides occur as dispersed accessory crystals and locally as small ore deposits. During the Quaternary, the valley floor, slopes, and cirques were covered by clastic sediments of differing thicknesses. A striking feature of the valley is that the slopes have been affected by different types of mass movements (rockfalls, debris flows and deep-seated rockslides). Data from extensive (hydro)geological field surveys, tunnels (exploration drift and water conduction galleries) and exploration drillings indicate that the groundwater preferentially flows within zones of highly weathered bedrock (i.e. the saprolite), brittle fault and fracture zones, deep-seated rockslides, and in the conductive Quaternary deposits, i.e. the talus, colluvium, debris flow and alluvial deposits. Interestingly, unusually high amounts of total dissolved solids (>1000 mg / l) were measured in some spring waters. Tritium and δ18 O values indicate short residence times (<5 years) and the analysis of δ 18 O and δ 2 H data shows that the groundwater is of meteoric origin and that no fractionation or evaporation processes, leading to increased mineralisation, have taken place. Ca and Mg are the dominant cations and SO 4 and HCO 3 are the major anions present. Data correlation shows that the electric conductivity (EC) of the waters increases with increasing Ca, Mg and SO 4 concentration, but not with HCO 3 . Low δ 34 S values indicate that the dissolved sulphate can be attributed to the oxidation of sulphides. Accordingly, the dissolution of carbonate fracture fillings and the oxidation of pyrite and other sulphides are regarded as the main processes responsible for the mineralised groundwater in the study area. Aquifer geochemistry of crystalline rocks and Quaternary deposits in a high altitude alpine environment (Kauner Valley, Austria)
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