Mountainous headwaters consist of different landscape units including forests, meadows and wetlands. In these headwaters it is unclear which landscape units contribute what percentage to baseflow. In this study, we analysed spatiotemporal differences in baseflow isotope and hydrochemistry to identify catchment-scale runoff contribution. Three baseflow snapshot sampling campaigns were performed in the Swiss pre-alpine headwater catchment of the ZwÀckentobel (4.25km2) and six of its adjacent subcatchments. The spatial and temporal variability of 2H, Ca, DOC, AT, pH, SO4, Mg and H4SiO4 of streamflow, groundwater and spring water samples was analysed and related to catchment area and wetland percentage using bivariate and multivariate methods. Our study found that in the six subcatchments, with variable arrangements of landscape units, the inter-and intra catchment variability of isotopic and hydrochemical compositions was small and generally not significant. Stream samples were distinctly different from shallow groundwater. An upper spring zone located near the water divide above 1,400 m and a larger wetland were identified by their distinct spatial isotopic and hydrochemical composition. The upstream wetland percentage was not correlated to the hydrochemical streamflow composition, suggesting that wetlands were less connected and act as passive features with a negligible contribution to baseflow runoff. The isotopic and hydrochemical composition of baseflow changed slightly from the upper spring zone towards the subcatchment outlets and corresponded to the signature of deep groundwater. Our results confirm the need and benefits of spatially distributed snapshot sampling to derive process understanding of heterogeneous headwaters during baseflow. DOI: https://doi.org/10.1002/hyp.10529Posted at the Zurich Open Repository and Archive, University of Zurich ZORA URL: https://doi.org/10.5167/uzh-111985 Accepted Version Originally published at: Fischer, Benjamin M C; Rinderer, Michael; Schneider, Philipp; Ewen, Tracy; Seibert, Jan (2015). Contributing sources to baseflow in pre-alpine headwaters using spatial snapshot sampling. Hydrological Processes, 29(26):5321-5336. DOI: https://doi.org/10. 1002/hyp.10529 This article has been accepted for publication and undergone full peer review but has not been through the copyediting, typesetting, pagination and proofreading process which may lead to differences between this version and the Version of Record. Please cite this article as doi: 10.1002/hyp.10529 This article is protected by copyright. All rights reserved.Contributing sources to baseflow in pre-alpine headwaters using spatial snapshot sampling
ABSTRACTMountainous headwaters consist of different landscape units including forests, meadows and wetlands. In these headwaters it is unclear which landscape units contribute what percentage to baseflow. In this study, we analysed spatiotemporal differences in baseflow isotope and hydrochemistry to identify catchment-scale runoff contribution. Three baseflow s...