Hydrolysis of azoesters via azoformate intermediates

Hegarty, A. F.; Tuohey, P. J.

doi:10.1039/p29800001238

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“…The structural determination of the synthesized compounds was based on IR and NMR spectra (Table 1). The IR spectra of biphenylhydrazinecarboxylates Ila-j revealed a strong band around 1700 cm-1 (uc-o) which is consistent with that found in other hydrazinecarboxylates (Hegarty and Tuohey, 1980; Garlaschelli and Gozzo, 1988). Yields of biphenylhydrazinecarboxylates Ila-j were in the range 69-80%.…”

Section: Introductionsupporting

confidence: 83%

Synthesis and Miticidal and Insecticidal Activities of Biphenylhydrazinecarboxylates

Dekeyser¹,

McDonald²,

Angle³

1994

J. Agric. Food Chem.

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Ten biphenylhydrazinecarboxylates were obtained by the condensation of o-biphenylhydrazine with alkyl chloroformates. The miticidal and insecticidal activities of the new compounds were evaluated against Tetranychus urticae and Sogatodes orizicola. Structure-activity relationships for the screened compounds are discussed. Some of the compounds displayed greater activity than did the commercial standards, propargite and carbofuran.

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Section: Introductionsupporting

confidence: 83%