Hydrometallurgical Production of Electrolytic Manganese Dioxide (EMD) from Furnace Fines

Abstract

The ferromanganese (FeMn) alloy is produced through the smelting-reduction of manganese ores in submerged arc furnaces. This process generates large amounts of furnace dust that is environmentally problematic for storage. Due to its fineness and high volatile content, this furnace dust cannot be recirculated through the process, either. Conventional MnO2 production requires the pre-reduction of low-grade ores at around 900 °C to convert the manganese oxides present in the ore into their respective acid-soluble forms; however, the furnace dust is a partly reduced by-product. In this study, a hydrometallurgical route is proposed to valorize the waste dust for the production of battery-grade MnO2. By using dextrin, a cheap organic reductant, the direct and complete dissolution of the manganese in the furnace dust is possible without any need for high-temperature pre-reduction. The leachate is then purified through pH adjustment followed by direct electrowinning for electrolytic manganese dioxide (EMD) production. An overall manganese recovery rate of >90% is achieved.

Impact of high volume E.M.D. residue on the corrosion resistance and mechanical properties of construction materials in sulfate environment

“…One such additive that has received less attention is Electrolytic Manganese Dioxide (EMD). Electrolytic manganese dioxide (EMD) is a type of manganese dioxide that is commonly used as a cathode material in batteries [29][30][31], in which, the chemical composition of electrolytic manganese dioxide (EMD) is primarily manganese dioxide (MnO 2 ) in the form of pyrolusite [32]; in the production of EMD, small amounts of ferrous oxides, silicon dioxide, calcium oxide and traces of metals (Al 2 O 3 and alkali oxides) may also be present [33,34]. Electrolytic Manganese Dioxide (EMD), typically has a dark black or dark gray appearance and a density of approximately 5.0 g cm −3 .…”