Hydrosilylation of C–C π-Bonds

Wang, Xue; Cheng, Zhaoyang; Lu, Zhan

doi:10.1016/b978-0-323-96025-0.00015-6

Reference Module in Chemistry, Molecular Sciences and Chemical Engineering 2023

DOI: 10.1016/b978-0-323-96025-0.00015-6

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Hydrosilylation of C–C π-Bonds

Xue Wang,

Zhaoyang Cheng,

Zhan Lu

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2024

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Cited by 1 publication

References 334 publications

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Visible Light‐Promoted Aerobic Oxidation of α‐Silyl Styrenes with Alcohols

Tan,

Yang,

Ying

et al. 2024

Chin. J. Chem.

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Comprehensive SummaryA mechanistically distinctive visible‐light‐promoted metal‐free aerobic oxidation of alkenyl silanes with alcohols was disclosed to efficiently construct α‐alkoxy ketones under mild conditions. The primary, secondary, and tertiary alcohols could be used as reactants. The protocol could be carried out on a gram‐scale. Various derivatizations of products could be conducted. Mechanistic studies indicated the reaction was initiated by single‐electron oxidation of the alkenyl silanes, rather than radical addition to alkenyl silanes.

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Visible Light‐Promoted Aerobic Oxidation of α‐Silyl Styrenes with Alcohols

Tan,

Yang,

Ying

et al. 2024

Chin. J. Chem.

View full text Add to dashboard Cite

show abstract

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Hydrosilylation of C–C π-Bonds

Cited by 1 publication

References 334 publications

Visible Light‐Promoted Aerobic Oxidation of α‐Silyl Styrenes with Alcohols

Visible Light‐Promoted Aerobic Oxidation of α‐Silyl Styrenes with Alcohols

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