Hydrosilylation of nitriles and tertiary amides using a zinc precursor

Kumar, Ravi; Meher, Rohan Kumar; Karmakar, Himadri; Panda, Tarun K.

doi:10.1039/d4ob00161c

Org. Biomol. Chem.

2024

DOI: 10.1039/d4ob00161c

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Hydrosilylation of nitriles and tertiary amides using a zinc precursor

Ravi Kumar,

Rohan Kumar Meher,

Himadri Karmakar

et al.

Abstract: We report the competent and selective hydrosilylation of nitriles and tertiary amides catalyzed by readily available zinc bis(hexamethyldislazide) under solvent-free and mild conditions, making it a sustainable and desirable alternative...

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Cited by 3 publications

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Hydrosilylation of nitriles and tertiary amides using a zinc precursor

Abstract: We report the competent and selective hydrosilylation of nitriles and tertiary amides catalyzed by readily available zinc bis(hexamethyldislazide) under solvent-free and mild conditions, making it a sustainable and desirable alternative...

Cited by 3 publications

References 51 publications

Efficient cyanosilylation of carbonyls using a well-defined dimeric sodium complex

Efficient cyanosilylation of carbonyls using a well-defined dimeric sodium complex

Mechanism and chemoselectivity of nitrile hydrosilylation catalyzed by [E-Rh] (E=Al, Ga, In) heterobimetallic catalysts: A theoretical perspective

Synthesis and structural characterization of 2,2′:6,2″-Terpyridine zinc Formate: Hydroboration and hydrosilylation of CO2 and carbonyl compounds

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