In
this study, the fate of carbon and nutrient elements, nitrogen,
phosphorus, and potassium, was investigated during the hydrothermal
carbonization (HTC) of three model solutions with different nutrient
concentrations to mimic biogas residues from silage and cattle manure.
The
HTC was conducted at 180 °C, 220 °C, 240 °C, and 260
°C for 3 h reaction time. ICP-OES, GC, IC, and chemical analysis
methods were utilized to measure fertilizing elements in HTC products.
The distribution of nutrients between HTC product phases was significantly
influenced by the compositions of the initial feedstock before HTC.
The incorporation of nitrogen to the hydrochar (HC) depends on the
nitrogen-containing compounds during HTC; the chemical bonding was
the main mechanism for the incorporation of NH4–N
into the HC during HTC, the sorption of NH4–N to
the HC occurred, however, to a lesser extent (0.8% to 7.4%). Most
of the NO3–N stayed in the process water (PW) during
HTC (78% to 87%), and the sorption (adsorption/salts precipitation)
was confirmed to be the main mechanism for the recovery of NO3–N to the HC during HTC. The uptake of N to the HC
is limited and depends on the availability of the carbon network in
the HC, the correlation coefficient between HC formation and the recovery
of bonded N to the HC showed a high linear regression coefficient R
2 = 0.90–0.91. However, the recovery
of N to the HC via sorption showed less correlation to the HC formation
during HTC (R
2 = 0.35–0.54). Most
of the dissolved K+ (99%) stayed in the PW during HTC.
Due to the absence of metal associations in this work, most of the
dissolved PO4
3– (99%) stayed in the PW
during HTC, which proves that controlling metal cations in the feedstock
before HTC has a considerable influence on the distribution of phosphate
between the PW and HC.