Please cite this article as: Mäkelä, M., Benavente, V., Fullana, A., Hydrothermal carbonization of industrial mixed sludge from a pulp and paper mill, Bioresource Technology (2015), doi: http://dx.doi.org/10.1016/j.biortech. 2015.10.062 This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain.
AbstractMixed sludge from a pulp and paper mill was hydrothermally carbonized at 180-260 °C for 0.5-5 h with the use of HCl or NaOH for determining the effect of acid and base additions during sludge carbonization. Based on the results carbonization was mainly governed by dehydration, depolymerization and decarboxylation of sludge components.Additive type had a statistically significant effect on hydrochar carbon content and carbon and energy yield, of which especially energy yield increased through the use of HCl. The theoretical energy efficiencies of carbonization increased with decreasing reaction temperature, retention time and the use of HCl and suggested that the energy requirement could be covered by the energy content of attained hydrochar. The BOD 5 /COD -ratios of analyzed liquid samples indicated that the dissolved organic components could be treated by conventional biological methods.