Hydrothermal synthesis and characterization of a novel two-dimensional bimetallic oxide network based on molybdenum oxide chain: [Zn(HPBIM)2(H2O)2Mo6O20]

Synthesis and crystal structures of two new inorganic–organic hybrid polyoxomolybdate complexes: [Himi]4[{Co(imi)2(H2O)2}Mo7O24]·4H2O and [Zn(imi)4]2[(imi)2Mo8O26]·6H2O

“…It has been recognized for a long time that the ability to functionalize polyoxometalate anions would extend their versatility and lead to new and more selective applications [3]. In particular, the chemistry of coordination compounds of polyoxometalates with organic ligands provides knowledge about the interaction of small organic molecules with polyoxometalate surfaces [4][5][6][7][8][9][10][11].Recently, the synthesis and characterization of polyoxomolybdates linked by coordinated transition metal fragments has attracted great attention [12][13][14][15][16][17][18][19][20]. Polyoxomolybdates, which have oxygen-rich compositions, can be used as building blocks to construct structures of new materials.…”

“…Recently, the synthesis and characterization of polyoxomolybdates linked by coordinated transition metal fragments has attracted great attention [12][13][14][15][16][17][18][19][20]. Polyoxomolybdates, which have oxygen-rich compositions, can be used as building blocks to construct structures of new materials.…”