Hydrothermal synthesis and crystal structure of a three‐dimensional polyoxovanadate

Abstract

A three-dimensional polyoxovanadate formulated as HV 3 O 8 ·H 2 O has been synthesized by hydrothermal method. Its structure was established by single-crystal X-ray diffraction. The crystal belong to monoclinic system with a space group P2 1 /m, a= 4.9980 (10) Å, b=8.4188 (17) Å, c = 7.8614 (16) Å, α = 90.00°, β =96.40 (3)°, γ =90.00°, V= 328.72(11) Å 3 , Z =2, F_000 = 282, R 1 = 0.0230, wR 2 = 0.0678.