A series of Eu 3+ and Tb 3+ co-doped CaMoO 4 /SrMoO 4 luminescent thin films were prepared by a facile solution method, and they were annealed at 550°C for 2 h. The luminescent properties of the thin films were studied, which involve the energy transfer from Tb 3+ to Eu 3+ . The emission color can be changed from green to red, with increasing Eu 3+ doping concentration in Tb 3+ -doped CaMoO 4 /SrMoO 4 thin films. In addition, it was observed that the PL intensity of Eu 3+ will enhance when Tb 3+ ions are incorporated into Eu 3+ -doped CaMoO 4 /SrMoO 4 thin films. The optical band gaps of the luminescent thin films are found to be in the range of 4.49 to 4.72 eV. These results revealed that Eu 3+ and Tb 3+ co-doped CaMoO 4 /SrMoO 4 luminescent thin films have a significantly potential application in electroluminescent devices.