In the current work a new method to extract and analyse pore water d 2 H and d
18O from drill core samples via H 2 O (liquid) -H 2 O (vapour) equilibrium laser spectroscopy is presented. The method combines a H 2 O (liquid) -H 2 O (vapour) equilibrium cell with a Los Gatos Research (LGR) cavity ring down mass spectrometer (CRDS) and follows and adaption of the original method presented by Wassenaar et al. (2008). Sediment and rock samples taken from a research site in New South Wales, Australia were first equilibrated in a fixed volume of dehumidified air and then directly sampled by the LGR mass spectrometer. Results provide clear evidence that the technique is repeatable and can be conducted on geologic media that contain volumetric water content as low as 5%, with H 2 O (liquid) -H 2 O (vapour) equilibrium occurring over time periods as short as 120 minutes. The faster sample analysis time and lower associated consumable and instrumentation costs of the method compared to conventional techniques for pore water extraction (centrifugation, squeezing, installation of monitoring bores, etc.) and analysis therefore presents great potential for field deployment, enabling hydrogeological profiling without the need to remove drill core samples from site. (vapour) equilibrium laser spectroscopy. Environ. Sci. Technol., 42, pp. 9262-9267, 2008. 1788-2281/$20.00 © 2013 Akadémiai Kiadó, Budapest Central European Geology, Vol. 56/2-3, pp. 1-280 (2013 DOI: 10.1556/CEuGeol.56.2013
-ORIGIN OF NATURAL GAS-FED "ETERNAL FLAMES" IN THE NORTHERN APPALACHIAN BASIN, USAArndt Schimmelmann 1 -Giuseppe Etiope 2 -Agnieszka Drobniak 3 1 Department of Geological Sciences, Indiana University, Bloomington, Indiana, USA; e-mail: aschimme@indiana.edu 2 Istituto Nazionale di Geofisica e Vulcanologia, Roma, Italy, and Faculty of Environmental Science and Engineering, Babes-Bolyai University, Cluj-Napoca, Romania 3 Indiana Geological Survey, Indiana University, Bloomington, Indiana, USA Natural hydrocarbon gas seeps are surface expressions of petroleum seepage systems, where gas ascends through faults and conduits from pressurized reservoirs that are typically associated with conventional reservoirs in sandstones or limestones. These rare natural gas seeps provide opportunities for direct sampling of gas from subsurface hydrocarbon accumulations without the need for drilling or other costly means of petroleum exploration.We have documented a site in the northern Appalachian Basin, at Chestnut Ridge County Park, New York (Fig. 1, left), where gas seepage has supported a spectacular "eternal flame" throughout available recorded history, and which may have burnt naturally for many hundreds or even thousands of years. This remarkable flame marks a natural gas macroseep of dominantly thermogenic origin. Gas emanates directly from deep shale source rocks, probably the Rhinestreet Shale of the Upper Devonian West Falls Group, which makes this a rare case in contrast to most petroleum seepage systems where gas derives from conventional reservo...