2022
DOI: 10.1016/j.snb.2022.132584
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Hydrothermally engineered WO3 nanoflowers: A selective detection towards toxic NO2 gas

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Cited by 31 publications
(9 citation statements)
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“…To accomplish this, we examined six samples [referenced as (i–iv) in Figure ] represents before and after PEC reactions for analysis. From Figure a–g, we observed major peaks corresponding to W 4d 5/2 (247.6 eV), W 4d 3/2 (260.3 eV) (Figure a), Bi 4f 5/2 (164.7 eV), Bi 4f 7/2 (159.4 eV) (Figure b), Ti 2p 1/2 (464.7 eV), Ti 2p 3/2 (458.9 eV) (Figure c), V 2p 1/2 (524.4 eV), V 2p 3/2 (516.8 eV) (Figure e), Ni 2p 1/2 (874.1 eV), and Ni 2p 3/2 (856.5 eV) (Figure f). , These were attributed to oxidation states of +6, +3, +4, +5, and +3 for W, Bi, Ti, V, and Ni, respectively. , The XPS spectra of O 1s in Figure d indicated an insignificant oxidation state of O (−2) with lattice oxygen (metal–O) at 530.5 eV, along with a shoulder at 532 eV confirming surface-adsorbed oxygen (–OOH). These results emphasized that the oxidation state of (a) W, (b) Bi, and (c) Ti remained relatively stable even after extended PEC reactions.…”
Section: Resultsmentioning
confidence: 93%
“…To accomplish this, we examined six samples [referenced as (i–iv) in Figure ] represents before and after PEC reactions for analysis. From Figure a–g, we observed major peaks corresponding to W 4d 5/2 (247.6 eV), W 4d 3/2 (260.3 eV) (Figure a), Bi 4f 5/2 (164.7 eV), Bi 4f 7/2 (159.4 eV) (Figure b), Ti 2p 1/2 (464.7 eV), Ti 2p 3/2 (458.9 eV) (Figure c), V 2p 1/2 (524.4 eV), V 2p 3/2 (516.8 eV) (Figure e), Ni 2p 1/2 (874.1 eV), and Ni 2p 3/2 (856.5 eV) (Figure f). , These were attributed to oxidation states of +6, +3, +4, +5, and +3 for W, Bi, Ti, V, and Ni, respectively. , The XPS spectra of O 1s in Figure d indicated an insignificant oxidation state of O (−2) with lattice oxygen (metal–O) at 530.5 eV, along with a shoulder at 532 eV confirming surface-adsorbed oxygen (–OOH). These results emphasized that the oxidation state of (a) W, (b) Bi, and (c) Ti remained relatively stable even after extended PEC reactions.…”
Section: Resultsmentioning
confidence: 93%
“…[ 27,28 ] Such features are explained by Hooge's mobility fluctuation (HMF) model. [ 27,33 ] In both cases, 1/ f γ noise with γ ∼ 1 is dominant in the low‐frequency domain. However, the FET‐type gas sensor with the WO 3 sensing layer shows a Lorentzian curve with a distinct f c at f = 100 Hz, as shown in Figure 3c.…”
Section: Resultsmentioning
confidence: 99%
“…Finally, we experimentally realize an in‐memory‐computed FFT system for LFN spectroscopy using a 3D vertical‐NAND (V‐NAND) flash array. The proposed LFN spectroscopy for selective detection has merits in terms of reliability and energy efficiency compared to previous studies that adopt nanostructured sensing materials [ 33 ] or a dense array of sensors, which requires complicated data processing. [ 34 ] The results in this study pave the way for the building of area‐ and energy‐efficient gas sensing systems for selective detection with excellent reliability.…”
Section: Introductionmentioning
confidence: 99%
“…The static mode is employed for the gas sensing investigations. The specific concentration (100 ppm) of different oxidizing and reducing gases were injected in chamber and gas response of a sensor was measured using following relation 2 [48,49] boldRboldeboldsboldpboldoboldnboldsbolde%=|boldRbolda-boldRboldg|RaX100 $\vcenter{\openup.5em\halign{$\displaystyle{#}$\cr {\bf R e s p o n s e}{\rm \ }\left({\rm \char37 }\right)={{|{{\bf R}}_{{\bf a}}-{{\bf R}}_{{\bf g}}|}\over{{{\bf R}}_{{\bf a}}}}{\bf X}{\rm \ }100\ \hfill\cr}}$ …”
Section: Methodsmentioning
confidence: 99%
“…The static mode is employed for the gas sensing investigations. The specific concentration (100 ppm) of different oxidizing and reducing gases were injected in chamber and gas response of a sensor was measured using following relation (2) [48,49] Response % ð Þ ¼ jR a À R g j R a X 100…”
Section: Chemistryselectmentioning
confidence: 99%