Ionic liquids (ILs) consisting entirely of ions exhibit
many fascinating
and tunable properties, making them promising functional materials
for a large number of energy-related applications. For example, ILs
have been employed as electrolytes for electrochemical energy storage
and conversion, as heat transfer fluids and phase-change materials
for thermal energy transfer and storage, as solvents and/or catalysts
for CO2 capture, CO2 conversion, biomass treatment
and biofuel extraction, and as high-energy propellants for aerospace
applications. This paper provides an extensive overview on the various
energy applications of ILs and offers some thinking and viewpoints
on the current challenges and emerging opportunities in each area.
The basic fundamentals (structures and properties) of ILs are first
introduced. Then, motivations and successful applications of ILs in
the energy field are concisely outlined. Later, a detailed review
of recent representative works in each area is provided. For each
application, the role of ILs and their associated benefits are elaborated.
Research trends and insights into the selection of ILs to achieve
improved performance are analyzed as well. Challenges and future opportunities
are pointed out before the paper is concluded.